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麝香

麝香用途

是贵重药材。可用于高级香水中。一般香精中常用合成麝香代替。
用作高档香料的定香剂

麝香名称

[ CAS 号 ]:
116-66-5

[ 中文名 ]:
麝香

[ 英文名 ]:
1,1,3,3,5-pentamethyl-4,6-dinitroindane

[中文别名 ]:

[英文别名 ]:

Nitromusl moskene
Moskene
musk,oscene
EINECS 204-149-4
Musk moskene
1,1,3,3,5-Pentamethyl-4,6-dinitroindane
MFCD00021242
4,6-DINITRO-1,1,3,3,5-PENTAMETHYLINDANE
Musk moskene solution
1,1,3,3,5-pentamethyl-4,6-dinitroindan

麝香物理化学性质

[ 密度 ]:
1.182g/cm3

[ 沸点 ]:
351.1ºC at 760mmHg

[ 分子式 ]:
C₁₄H₁₈N₂O₄

[ 分子量 ]:
278.30400

[ 闪点 ]:
145.3ºC

[ 精确质量 ]:
278.12700

[ PSA ]:
91.64000

[ LogP ]:
4.81670

[ 蒸汽压 ]:
8.49E-05mmHg at 25°C

[ 折射率 ]:
1.55

[ 储存条件 ]:
2-8°C

麝香毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: NK5045000

CHEMICAL NAME :: Indan, 4,6-dinitro-1,1,3,3,5-pentamethyl-

CAS REGISTRY NUMBER :: 116-66-5

BEILSTEIN REFERENCE NO. :: 2163411

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C14-H18-N2-O4

MOLECULAR WEIGHT :: 278.34

WISWESSER LINE NOTATION :: L56T&J B1 B1 D1 D1 FNW G1 HNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,885,1979 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,885,1979

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,885,1979 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1095 No. of Facilities: 1435 (estimated) No. of Industries: 3 No. of Occupations: 9 No. of Employees: 17329 (estimated) No. of Female Employees: 15024 (estimated)

麝香安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302-H312-H319-H332

[ 警示性声明 ]:
P210-P280-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F: Flammable;Xn: Harmful;

[ 风险声明 (欧洲) ]:
11-20/21/22-36

[ 安全声明 (欧洲) ]:
S16;S36/S37

[ 危险品运输编码 ]:
UN 1648 3/PG 2

[ 海关编码 ]:
2914700090

麝香合成路线

详细合成路线

麝香上下游产品

麝香上游产品

麝香下游产品

麝香海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

麝香文献

Simultaneous congener-specific determination of selected organochlorine compounds and nitro musks in human whole blood samples by solid-phase extraction and capillary gas chromatography with electron capture detection.

J. Anal. Toxicol. 29(2) , 110-7, (2005)

Chlororganic compounds like pesticides or polychlorinated biphenyls (PCB) and nitro musks are environmental contaminants, which remain public health concerns because of their persistence in humans and...

Determination of polycyclic and nitro musks in environmental water samples by means of microextraction by packed sorbents coupled to large volume injection-gas chromatography-mass spectrometry analysis.

Anal. Chim. Acta 773 , 68-75, (2013)

In this work the development and validation of a new procedure for the simultaneous determination of 9 nitro and polycyclic musk compounds: musk ambrette (MA), musk ketone (MK), musk mosken (MM), cele...

High-sensitivity analysis of six synthetic musks by ultra-performance liquid chromatography-atmospheric pressure photoionization-tandem mass spectrometry.

Anal. Chem. 83(12) , 4955-61, (2011)

The occurrence and potential toxicity of synthetic musks in environmental media have aroused concerns for the impacts of these chemicals on ecosystems and human health. Here, we present the first meth...

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麝香