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(R)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷

名称

[ CAS 号 ]:
301847-89-2

[ 中文名 ]:
R-(-)-1,13-二(二苯基膦)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬四烯

[ 英文名 ]:
(R)-C3-TUNAPHOS

[中文别名 ]:

[英文别名 ]:

物理化学性质

[ 沸点 ]:
709.9±60.0 ℃(Predicted)

[ 熔点 ]:
153-161ºC(lit.)

[ 分子式 ]:
C39H32O2P2

[ 分子量 ]:
594.61800

[ 精确质量 ]:
594.18800

[ PSA ]:
45.64000

[ LogP ]:
7.03130

[ 储存条件 ]:
室温

MSDS

详细MSDS(安全技术说明书)

安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

文献

Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters.

J. Org. Chem. 65 , 6223, (2000)

Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates.

J. Am. Chem. Soc. 125 , 9570, (2003)

Hydrogenation of a series of cyclic beta-(acylamino)acrylates with tetrasubstituted olefins has been accomplished successfully with the use of Ru catalysts with chiral biaryl ligands such as C3-TunaPh...

Highly enantioselective asymmetric hydrogenation of alpha-phthalimide ketone: an efficient entry to enantiomerically pure amino alcohols.

J. Am. Chem. Soc. 126 , 1626, (2004)

A new type of alpha-phthalimide ketones was hydrogenated in excellent enantioselectivity by using a Ru-(C3-TunePhos) complex as the catalyst. Up to 10 000 turnovers have been achieved in more than 99%...


更多文献

推荐生产厂家/供应商：

公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥1235.9/100mg ￥442.9/25mg ￥4974.9/500mg ￥需询单/1g

联系人：阿拉丁

产品详情：(R)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷

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CAS号[301847-89-2]化源网提供[(R)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷]MSDS、说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。>>电脑版：(R)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷

标题：301847-89-2_CAS号:301847-89-2_(R)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷 - 化源网 地址：https://www.chemsrc.com/amp/cas/301847-89-2_523083.html