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吡氟草胺

吡氟草胺用途

Diflufenican 是一种选择性除草剂,用于专门防治某些阔叶杂草。

吡氟草胺名称

[ CAS 号 ]:
83164-33-4

[ 中文名 ]:
吡氟酰草胺

[ 英文名 ]:
diflufenican

[中文别名 ]:

[英文别名 ]:

吡氟草胺生物活性

吡氟草胺物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
376.2±42.0 °C at 760 mmHg

[ 熔点 ]:
110°C

[ 分子式 ]:
C19H11F5N2O2

[ 分子量 ]:
394.295

[ 闪点 ]:
181.3±27.9 °C

[ 精确质量 ]:
394.074066

[ PSA ]:
51.22000

[ LogP ]:
3.65

[ 外观性状 ]:
无气味的白色固体

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.573

[ 储存条件 ]:
0-6°C

吡氟草胺MSDS

吡氟草胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
US4589800
CHEMICAL NAME :
3-Pyridinecarboxamide, N-(2,4-difluorophenyl)-2-(3-(trifluoromethyl)phenoxy) -
CAS REGISTRY NUMBER :
83164-33-4
LAST UPDATED :
199806
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C19-H11-F5-N2-O2
MOLECULAR WEIGHT :
394.32

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 41(247),21,1987
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 41(247),21,1987
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,283,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 41(247),21,1987 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
546 gm/kg/2Y-C
TOXIC EFFECTS :
Blood - changes in spleen Nutritional and Gross Metabolic - weight loss or decreased weight gain Nutritional and Gross Metabolic - changes in iron
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571106 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
135 gm/kg
SEX/DURATION :
multigeneration
TOXIC EFFECTS :
Reproductive - Effects on Newborn - delayed effects
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555262

吡氟草胺安全信息

[ 危害声明 ]:
H412

[ 警示性声明 ]:
P273

[ 个人防护装备 ]:
Eyeshields;Gloves

[ 风险声明 (欧洲) ]:
R52/53

[ 安全声明 (欧洲) ]:
S61

[ 危险品运输编码 ]:
NONH for all modes of transport

[ RTECS号 ]:
US4589800

吡氟草胺合成路线

吡氟草胺上下游产品

吡氟草胺制备

2-(3-三氟甲基苯氧基)-3-吡啶羧酸的制备 由3-三氟甲基苯酚与2-氯-3-吡啶羧酸作用制得。

吡氟草胺的合成 2-(3-三氟甲基苯氧基)-3-吡啶羧酸与氯化亚砜、2,4-二氟苯胺作用,合成吡氟草胺。

吡氟草胺文献

Multiresidue method for the determination of 13 pesticides in three environmental matrices: water, sediments and fish muscle.

Talanta 85(3) , 1500-7, (2011)

Pesticides residues in aquatic ecosystems are an environmental concern which requires efficient analytical methods. In this study, we proposed a generic method for the quantification of 13 pesticides ...

Single drop microextraction and gas chromatography-mass spectrometry for the determination of diflufenican, mepanipyrim, fipronil, and pretilachlor in water samples.

Environ. Monit. Assess. 185(12) , 10225-33, (2013)

An analytical method for the determination of diflufenican, mepanipyrim, pretilachlor, and fipronil in water samples was developed using single drop microextraction in the direct immersion mode and ga...

Rainfastness and adsorption of herbicides on hard surfaces.

Pest Manag. Sci. 61(8) , 793-8, (2005)

Herbicides are still used to control weeds on hard surfaces, including municipal, private and industrial sites. Used under unfavourable conditions, especially when rain occurs shortly after applicatio...


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