Stannic chloride pentahydrate
Names
[ CAS No. ]:
10026-06-9
[ Name ]:
Stannic chloride pentahydrate
[Synonym ]:
Stannic chloride, pentahydrate [UN2440] [Corrosive]
Tin(IV) chloride pentahydrate
Tetrachlorostannane pentahydrate
MFCD00149864
tin(iv) tetrachloride pentahydrate
EINECS 231-588-9
Stannane, tetrachloro-, hydrate (1:5)
tetrachlorostannane,pentahydrate
Chemical & Physical Properties
[ Boiling Point ]:
114.1ºC at 760 mmHg
[ Melting Point ]:
56 °C
[ Molecular Formula ]:
H10Cl4O5Sn
[ Molecular Weight ]:
350.598
[ Exact Mass ]:
349.830444
[ PSA ]:
46.15000
[ LogP ]:
2.05570
[ Vapour Pressure ]:
23.9mmHg at 25°C
[ Stability ]:
Stable, but may decompose in contact with moisture or water. Incompatible with strong acids.
[ Water Solubility ]:
soluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XP8870000
- CAS REGISTRY NUMBER :
- 10026-06-9
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 24
- MOLECULAR FORMULA :
- Cl4-Sn.5H2-O
- MOLECULAR WEIGHT :
- 350.59
- WISWESSER LINE NOTATION :
- .SN-G4.QH5
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 120 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 32 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
MUTATION DATA
- TYPE OF TEST :
- Sister chromatid exchange
- TEST SYSTEM :
- Human Lymphocyte
- DOSE/DURATION :
- 2 mg/L
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 282,61,1992 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 2 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,257,1971 OSHA PEL (Gen Indu):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Sn)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Sn)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Sn)/m3 JAN 1993 OEL-FINLAND:TWA 2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 2 mg(Sn)/m3 JAN 1993 OEL-HUNGARY:TWA 1 mg(Sn)/m3;STEL 2 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Sn)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 2 mg(Sn)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Sn)/m3;STEL 4 mg(Sn)/m3 JAN 1993 OEL-THAILAND:TWA 2 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Sn)/m3;STEL 10 mg(Sn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9720 No. of Facilities: 18 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 108 (estimated) No. of Female Employees: 72 (estimated)
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Precautionary Statements ]:
P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338
[ Hazard Codes ]:
C: Corrosive;
[ Risk Phrases ]:
R34;R52/53
[ Safety Phrases ]:
S26-S36/37/39-S45-S7/8-S61
[ RIDADR ]:
UN 2440 8/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
XP8870000
[ Packaging Group ]:
III
[ Hazard Class ]:
8
Articles
Chem. Mater. 10 , 880, (1998)
Condensations of benzil with phenols and aryl ethers mediated by tin (IV) chloride pentahydrate. Morrison BJ and Musgrave OC.
Tetrahedron 58(21) , 4255-4260, (2002)
Preparation of hard agglomerates free and weakly agglomerated antimony doped tin oxide (ATO) nanoparticles by coprecipitation reaction in methanol reaction medium. Kim DW, et al.
Mater. Chem. Phys. 97(2) , 452-457, (2006)