ISOPROPYLSULFONYL CHLORIDE
Names
[ CAS No. ]:
10147-37-2
[ Name ]:
ISOPROPYLSULFONYL CHLORIDE
[Synonym ]:
propane-2-sulfonyl chloride
2-Propanesulfonyl chloride
EINECS 233-415-2
Isopropylsulfonyl Chloride
MFCD00007453
Chemical & Physical Properties
[ Density]:
1.27 g/mL at 25 °C(lit.)
[ Boiling Point ]:
74-75 °C19 mm Hg(lit.)
[ Melting Point ]:
-47°C
[ Molecular Formula ]:
C3H7ClO2S
[ Molecular Weight ]:
142.60400
[ Flash Point ]:
187 °F
[ Exact Mass ]:
141.98600
[ PSA ]:
42.52000
[ LogP ]:
2.04420
[ Vapour density ]:
4 (vs air)
[ Vapour Pressure ]:
1.16mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.453(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C: Corrosive;
[ Risk Phrases ]:
R34
[ Safety Phrases ]:
S26-S28-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
8
[ HS Code ]:
2904909090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2904909090
[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Org. Biomol. Chem. 4(8) , 1580-6, (2006)
Contrary to earlier suggestions of an S(N)1 pathway for solvolyses of N,N-dimethylsulfamoyl chloride (1), an extended Grunwald-Winstein equation treatment of the specific rates of solvolysis in 32 sol...