Ethyl (R)-(-)-Mandelate

Names

[ Name ]:
Ethyl (R)-(-)-Mandelate

[Synonym ]:
(R)-(-)-mandelic acid ethyl ester
Benzeneacetic acid, α-hydroxy-, ethyl ester, (R)-
Ethyl (2R)-hydroxy(phenyl)acetate
D-(-)-Mandelic Acid Ethyl Ester
Ethyl (R)-(-)-Mandelate
Ethyl D-(-)-Mandelate
MFCD00064248
Ethyl (R)-(−)-mandelate
Benzeneacetic acid, α-hydroxy-, ethyl ester, (αR)-
Ethyl R-mandelate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
254.0±0.0 °C at 760 mmHg

[ Melting Point ]:
33-34 °C(lit.)

[ Molecular Formula ]:
C₁₀H₁₂O₃

[ Molecular Weight ]:
180.201

[ Flash Point ]:
118.1±14.5 °C

[ Exact Mass ]:
180.078644

[ PSA ]:
46.53000

[ LogP ]:
1.43

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.528

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2918199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918199090

[ Summary ]:
2918199090 other carboxylic acids with alcohol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Catalysis of the hydrolysis of ethyl mandelate and esterification of alpha-bromopropionic acid by lipase in microemulsions.

Chin. J. Biotechnol. 9(1) , 33-9, (1993)

Candida cyclindracea lipase (CCL) was added to "sodium dodecyl sulfonate (AS)/n-butanol/n-octane/n-octane" water-in-oil microemulsion to catalyze the hydrolysis of ethyl mandelate and the esterificati...

Esters of mandelic acid as substrates for (S)-mandelate dehydrogenase from Pseudomonas putida: implications for the reaction mechanism.

Biochemistry 43(7) , 1883-90, (2004)

(S)-Mandelate dehydrogenase (MDH) from Pseudomonas putida is a flavin mononucleotide (FMN)-dependent enzyme that oxidizes (S)-mandelate to benzoylformate. In this work, we show that the ethyl and meth...