1-Methoxy-2-propyl acetate

Names

[ CAS No. ]:
108-65-6

[ Name ]:
1-Methoxy-2-propyl acetate

[Synonym ]:
2-methoxy-1-methylethyl acetate
1,2-Propanediol 1-Monomethyl Ether 2-Acetate
Dowanol PMA
MFCD00038500
Propylene glycol monomethyl ether acetate
1,2-Propanediol monomethyl ether acetate
(R,S)-1-methoxy-2-propyl acetate
PMA-EL
Propylene Glycol 1-Monomethyl Ether 2-Acetate
2-(1-Methoxy)propyl acetate
DOWANOL(TM) PMA
1-methoxy-2-propylacetate
2-Acetoxy-1-methoxypropane
2pg1mea
PGMEA
ARCOSOLV(R) PMA
1-methoxy-2-propanol acetate
Arcosolv PMA
Propylene glycol methyl ether acetate
EINECS 203-603-9
MPA

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
154.8±13.0 °C at 760 mmHg

[ Melting Point ]:
-87 °C

[ Molecular Formula ]:
C₆H₁₂O₃

[ Molecular Weight ]:
132.158

[ Flash Point ]:
47.9±11.4 °C

[ Exact Mass ]:
132.078644

[ PSA ]:
35.53000

[ LogP ]:
0.26

[ Vapour Pressure ]:
3.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.399

[ Storage condition ]:
Flammables area

[ Stability ]:
Stable. Flammable. Incompatible with strong oxidizing agents, acids, bases.

[ Water Solubility ]:
19.8 g/L (25 ºC)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AI8925000

CHEMICAL NAME :: Acetic acid, 2-methoxy-1-methylethyl ester

CAS REGISTRY NUMBER :: 108-65-6

BEILSTEIN REFERENCE NO. :: 1751656

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C6-H12-O3

MOLECULAR WEIGHT :: 132.18

WISWESSER LINE NOTATION :: 1VOY1&1O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 8532 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DOWCC* Dow Chemical Company Reports. (Dow Chemical USA, Health and Environment Research, Toxicology Research Lab., Midland, MI 48640) Volume(issue)/page/year: MSD-1582

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 750 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD691-490

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DOWCC* Dow Chemical Company Reports. (Dow Chemical USA, Health and Environment Research, Toxicology Research Lab., Midland, MI 48640) Volume(issue)/page/year: MSD-1582 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9258 No. of Facilities: 30459 (estimated) No. of Industries: 178 No. of Occupations: 109 No. of Employees: 345446 (estimated) No. of Female Employees: 40133 (estimated)

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Precautionary Statements ]:
P210-P403 + P235

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T,Xi

[ Risk Phrases ]:
R61:May cause harm to the unborn child. R10:Flammable. R36:Irritating to the eyes.

[ Safety Phrases ]:
S53-S25-S45

[ RIDADR ]:
UN 3271 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
AI8925000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2918199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915390090

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

Articles

Surface modification-induced phase transformation of hexagonal close-packed gold square sheets.

Nat. Commun. 6 , 6571, (2015)

Conventionally, the phase transformation of inorganic nanocrystals is realized under extreme conditions (for example, high temperature or high pressure). Here we report the complete phase transformati...

Phosphorescent quantum dots/ethidium bromide nanohybrids based on photoinduced electron transfer for DNA detection.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 140 , 479-83, (2015)

Mercaptopropionic acid-capped Mn-doped ZnS quantum dots/ethidium bromide (EB) nanohybrids were constructed for photoinduced electron transfer (PIET) and then used as a room-temperature phosphorescence...

Nutrients value and antioxidant content of indigenous vegetables from Southern Thailand.

Food Chem. 173 , 838-46, (2014)

Evidence from epidemiological studies has strongly suggested that diets rich in fruits and vegetables play a vital role in disease prevention. The aim of this study was to determine nutrient and antio...