4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine

[ Density]:
1.004g/cm3

[ Boiling Point ]:
535.7ºC at 760 mmHg

[ Melting Point ]:
215-217ºC(lit.)

[ Molecular Formula ]:
C₂₇H₃₅N₃

[ Molecular Weight ]:
401.58700

[ Flash Point ]:
220.4ºC

[ Exact Mass ]:
401.28300

[ PSA ]:
38.67000

[ LogP ]:
7.09810

[ Vapour Pressure ]:
5.19E-11mmHg at 25°C

[ Index of Refraction ]:
1.537

Click to get detail MSDS

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

A five-coordinate nickel(II) fluoroalkyl complex as a precursor to a spectroscopically detectable Ni(III) species.

J. Am. Chem. Soc. 135(22) , 8141-4, (2013)

Mechanistic proposals for nickel-catalyzed coupling reactions often invoke five-coordinate alkyl- or aryl-bound Ni(II) and/or high-valent nickel(III) species, but because of their reactive nature, the...

Ligand redox effects in the synthesis, electronic structure, and reactivity of an alkyl-alkyl cross-coupling catalyst.

J. Am. Chem. Soc. 128(40) , 13175-83, (2006)

The ability of the terpyridine ligand to stabilize alkyl complexes of nickel has been central in obtaining a fundamental understanding of the key processes involved in alkyl-alkyl cross-coupling react...

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