MM 47755
Names
Chemical & Physical Properties
[ Density]:
1.39g/cm3
[ Boiling Point ]:
583.3ºC at 760mmHg
[ Molecular Formula ]:
C20H16O5
[ Molecular Weight ]:
336.33800
[ Flash Point ]:
214.3ºC
[ Exact Mass ]:
336.10000
[ PSA ]:
80.67000
[ LogP ]:
2.35050
[ Vapour Pressure ]:
1.89E-14mmHg at 25°C
[ Index of Refraction ]:
1.652
Safety Information
[ Symbol ]:
GHS07, GHS09
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H410
[ Precautionary Statements ]:
P273-P501
[ RIDADR ]:
UN 3077 9 / PGIII
Articles
J. Org. Chem. 72(16) , 6116-26, (2007)
A concise and highly enantioselective route has been developed for the synthesis of angucyclinone-type natural products. Utilizing this strategy, total syntheses of five natural products YM-181741, (+...
Total synthesis of (-)-8-O-methyltetrangomycin (MM 47755).Org. Lett. 8(12) , 2507-10, (2006)
A stereoselective total synthesis of the natural antibiotic (-)-8-O-methyltetrangomycin 1 is reported. The essential steps for this convergent synthesis are the transformation of a geraniol epoxide in...
The cobalt way to angucyclinones: asymmetric total synthesis of the antibiotics (+)-rubiginone B2, (-)-tetrangomycin, and (-)-8-O-methyltetrangomycin.Chemistry 16(29) , 8805-21, (2010)
A cobalt(I)-mediated convergent and asymmetric total synthesis of angucyclinones with an aromatic B ring has been developed. In the course of our research, we synthesized three naturally occurring ang...