Tri-tert-butylphosphine tetrafluoroborate

Names

[ Name ]:
Tri-tert-butylphosphine tetrafluoroborate

[Synonym ]:
Tris(2-methyl-2-propanyl)phosphonium tetrafluoroborate
tritert-butylphosphanium,tetrafluoroborate
Tri-tert-butylphosphonium Tetrafluoroborate
MFCD07189501
Tri-tert-butyl phosphoniumtetra fluoro borate

Biological Activity

[Description]:

Tri-tert-butylphosphine tetrafluoroborate is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

[In Vitro]

Tri-tert-butylphosphonium tetrafluoroborate 是一种配体，用于钯催化的 N-boc-吡咯烷的对映选择性 α-芳基化。它还与钯 (0)-15 元三烯烃大环化合物一起用于芳基溴化物和氯化物的 Suzuki 交叉偶联反应。此外，它还用于甲苯磺酸乙烯酯与烯烃的 Heck 偶联。

Chemical & Physical Properties

[ Melting Point ]:
261 °C(lit.)

[ Molecular Formula ]:
C₁₂H₂₇P_.BF_4.H

[ Molecular Weight ]:
290.13

[ Exact Mass ]:
290.195770

[ PSA ]:
13.59000

[ LogP ]:
6.16380

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S22-S24/25-S36/37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Heck coupling with nonactivated alkenyl tosylates and phosphates: examples of effective 1,2-migrations of the alkenyl palladium(II) intermediates.

Angew. Chem. Int. Ed. Engl. 45 , 3349, (2006)

Enantioselective, palladium-catalyzed alpha-arylation of N-Boc-pyrrolidine.

Tetrahedron Asymmetry 6 , 1283, (1995)

This communication discloses the first instance of the enantioselective Pd-catalyzed alpha-arylation of N-Boc-pyrrolidine. The methodology relies on Beak's sparteine-mediated, enantioselective deproto...

Synlett , 3001, (2006)