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Sodium sulfide

Names

[ CAS No. ]:
1313-82-2

[ Name ]:
Sodium sulfide

[Synonym ]:
EINECS 215-211-5
Disodium sulfide
MFCD00003498
Sodium sulfide

Chemical & Physical Properties

[ Density]:
1.86 g/mL at 25 °C(lit.)

[ Boiling Point ]:
174ºC

[ Melting Point ]:
950 °C(lit.)

[ Molecular Formula ]:
Na2S

[ Molecular Weight ]:
78.045

[ Exact Mass ]:
77.951607

[ PSA ]:
25.30000

[ Stability ]:
Spontaneously flammable. Incompatible with acids, metals, oxidizing agents. Contact with acid liberates toxic gas. Fine dust/air mixtures are explosive. Hygroscopic.

[ Water Solubility ]:
186 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WE1905000
CHEMICAL NAME :
Sodium sulfide
CAS REGISTRY NUMBER :
1313-82-2
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
Na2-S
MOLECULAR WEIGHT :
78.04
WISWESSER LINE NOTATION :
.NA2.S

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
208 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(8),30,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
147 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(8),30,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
205 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(8),30,1986 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2 mg/kg/17W-I
TOXIC EFFECTS :
Behavioral - changes in motor activity (specific assay) Blood - pigmented or nucleated red blood cells Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(8),30,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2975 No. of Facilities: 301 (estimated) No. of Industries: 8 No. of Occupations: 13 No. of Employees: 3058 (estimated) No. of Female Employees: 350 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H251-H290-H301 + H311-H314-H400

[ Supplemental HS ]:
Contact with acids liberates toxic gas., Corrosive to the respiratory tract.

[ Precautionary Statements ]:
P273-P280-P301 + P310 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R31;R34;R50

[ Safety Phrases ]:
S26-S45-S61

[ RIDADR ]:
UN 1849 8/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
WE1905000

[ Packaging Group ]:
II

[ Hazard Class ]:
4.2

[ HS Code ]:
2830101000

Customs

[ HS Code ]: 2830101000

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