Tungsten trioxide
Names
[ CAS No. ]:
1314-35-8
[ Name ]:
Tungsten trioxide
[Synonym ]:
D-Glucose,3-methanesulfonate
3-O-Mesyl-D-glucose
Tungsten Trioxide
EINECS 215-231-4
O3-Mesyl-D-glucose
Tungstic anhydride
O3W,tetragonal
MFCD00011466
Tungsten(VI) oxide
Chemical & Physical Properties
[ Density]:
7.16 g/mL at 25 °C(lit.)
[ Boiling Point ]:
~1700ºC
[ Melting Point ]:
1470-1475 °C
[ Molecular Formula ]:
O3W
[ Molecular Weight ]:
231.83800
[ Exact Mass ]:
231.93600
[ PSA ]:
51.21000
[ Water Solubility ]:
insoluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- YO7760000
- CHEMICAL NAME :
- Tungsten oxide
- CAS REGISTRY NUMBER :
- 1314-35-8
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 19
- MOLECULAR FORMULA :
- O3-W
- MOLECULAR WEIGHT :
- 231.85
- WISWESSER LINE NOTATION :
- .WO..O3
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1059 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - excitement Behavioral - muscle weakness
- REFERENCE :
- HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 31(7-9),197,1966
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(7),71,1983 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 490 ug/m3/24H/15W-C
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(7),71,1983 *** REVIEWS *** ACGIH TLV-TWA 5 mg(W)/m3; STEL 10 mg(W)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 mg(W)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,272,1971 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(W)/m3;STEL 10 mg(W)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(W)/m3;STEL 10 mg(W)/m3 JAN 1993 OEL-DENMARK:TWA 5 mg(W)/m3 JAN 1993 OEL-FINLAND:TWA 5 mg(W)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 5 mg(W)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg(W)/m3 JAN 1993 OEL-SWEDEN:TWA 5 mg(W)/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg(W)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(W)/m3;STEL 10 mg(W)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO TUNGSTEN, insoluble-air:TWA 5 mg(W)/m3;STEL 10 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84213 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 21 (estimated)
Safety Information
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R22;R36/37/38
[ Safety Phrases ]:
S26-S36-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
-
[ RTECS ]:
YO7760000
[ HS Code ]:
2825901200
Customs
[ HS Code ]: 2825901200
Articles
ChemSusChem , doi:10.1002/cssc.201403278, (2015)
Composites of mesoporous polymeric carbon nitride and tungsten(VI) oxide show very high photocatalytic activity for the evolution of hydrogen from water under visible light and in the presence of sacr...
Liao; C.C.; et. al.Solar Energy Mat. and Solar Cells 7+8th ed., 90 , 1147-1155, (2006)
Polleux; J.; et. al.
Angew. Chem. Int. Ed. Engl. 2nd ed., 45 , 261-265, (2006)