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Phosphorus pentasulfide

Names

[ CAS No. ]:
1314-80-3

[ Name ]:
Phosphorus pentasulfide

[Synonym ]:
Phosphoric Sulphide
sulfurphosphide
Phosphorus(V) sulfide
Phosphorussulfid
EINECS 215-242-4
sirnikfosforecny
MFCD00011441
osphorus pentasulf
PHOSPHORUS SULFIDE
Phosphoruspersulfide
Phosphoricsulfide
rcrawastenumberu189

Chemical & Physical Properties

[ Density]:
2.3±0.1 g/cm3

[ Boiling Point ]:
514°C

[ Melting Point ]:
286 °C

[ Molecular Formula ]:
P4S10

[ Molecular Weight ]:
444.545

[ Exact Mass ]:
443.615753

[ PSA ]:
221.94000

[ LogP ]:
4.96340

[ Index of Refraction ]:
2.029

[ Water Solubility ]:
reacts

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TH4375000
CHEMICAL NAME :
Phosphorus sulfide
CAS REGISTRY NUMBER :
1314-80-3
LAST UPDATED :
199712
DATA ITEMS CITED :
31
MOLECULAR FORMULA :
P2-S5
MOLECULAR WEIGHT :
222.24
WISWESSER LINE NOTATION :
P4 S7

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,16,1972
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,16,1972 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
389 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,16,1972
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
3160 mg/kg
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571217 *** REVIEWS *** ACGIH TLV-STEL 3 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 1 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,211,1971 OSHA PEL (Gen Indu):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1 mg/m3;STEL 3 mg/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg/m3;STEL 3 mg/m3 JAN 1993 OEL-DENMARK:TWA 1 mg/m3 JAN 1993 OEL-FINLAND:STEL 1 mg/m3 JAN 1993 OEL-FRANCE:TWA 1 mg/m3 JAN 1993 OEL-GERMANY:TWA 1 mg/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 1 mg/m3;STEL 2 mg/m3 JAN 1993 OEL-THAILAND:TWA 1 mg/m3 JAN 1993 OEL-TURKEY:TWA 1 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg/m3;STEL 3 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO PHOSPHORUS PENTASULFIDE-air:TWA 1 mg/m3;STEL 3 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 59162 No. of Facilities: 31 (estimated) No. of Industries: 1 No. of Occupations: 14 No. of Employees: 1092 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 59162 No. of Facilities: 94 (estimated) No. of Industries: 4 No. of Occupations: 7 No. of Employees: 5372 (estimated) No. of Female Employees: 446 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H260-H302-H332-H400

[ Supplemental HS ]:
Contact with water liberates toxic gas.

[ Precautionary Statements ]:
P210-P223-P231 + P232-P273-P370 + P378-P422

[ Hazard Codes ]:
F:Flammable;Xn:Harmful;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R20/22;R29;R50

[ Safety Phrases ]:
S61

[ RIDADR ]:
UN 1340 4.3/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
TH4375000

[ Packaging Group ]:
II

[ Hazard Class ]:
4.3

[ HS Code ]:
2813900010

Customs

[ HS Code ]: 2813900010

Articles

New synthetic routes to poly (isothianaphthene) I. Reaction of phthalic anhydride and phthalide with phosphorus pentasulfide. van Asselt R, et al.

Synthetic Metals 74(1) , 65-70, (1995)

Thiation with phosphorus pentasulfide in pyridine solution. Klingsberg E and Papa D.

J. Am. Chem. Soc. 73(10) , 4988-4989, (1951)

Phosphorus (V) sulfide. Edmondson SD and Sannigrahi M.

e-EROS Encyclopedia of Reagents for Organic Synthesis. , (2004)


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