Phosphorus pentasulfide
Names
[ CAS No. ]:
1314-80-3
[ Name ]:
Phosphorus pentasulfide
[Synonym ]:
Phosphoric Sulphide
sulfurphosphide
Phosphorus(V) sulfide
Phosphorussulfid
EINECS 215-242-4
sirnikfosforecny
MFCD00011441
osphorus pentasulf
PHOSPHORUS SULFIDE
Phosphoruspersulfide
Phosphoricsulfide
rcrawastenumberu189
Chemical & Physical Properties
[ Density]:
2.3±0.1 g/cm3
[ Boiling Point ]:
514°C
[ Melting Point ]:
286 °C
[ Molecular Formula ]:
P4S10
[ Molecular Weight ]:
444.545
[ Exact Mass ]:
443.615753
[ PSA ]:
221.94000
[ LogP ]:
4.96340
[ Index of Refraction ]:
2.029
[ Water Solubility ]:
reacts
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TH4375000
- CHEMICAL NAME :
- Phosphorus sulfide
- CAS REGISTRY NUMBER :
- 1314-80-3
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 31
- MOLECULAR FORMULA :
- P2-S5
- MOLECULAR WEIGHT :
- 222.24
- WISWESSER LINE NOTATION :
- P4 S7
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,16,1972
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,16,1972 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 389 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,16,1972
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 3160 mg/kg
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571217 *** REVIEWS *** ACGIH TLV-STEL 3 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 1 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,211,1971 OSHA PEL (Gen Indu):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1 mg/m3;STEL 3 mg/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg/m3;STEL 3 mg/m3 JAN 1993 OEL-DENMARK:TWA 1 mg/m3 JAN 1993 OEL-FINLAND:STEL 1 mg/m3 JAN 1993 OEL-FRANCE:TWA 1 mg/m3 JAN 1993 OEL-GERMANY:TWA 1 mg/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 1 mg/m3;STEL 2 mg/m3 JAN 1993 OEL-THAILAND:TWA 1 mg/m3 JAN 1993 OEL-TURKEY:TWA 1 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg/m3;STEL 3 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO PHOSPHORUS PENTASULFIDE-air:TWA 1 mg/m3;STEL 3 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 59162 No. of Facilities: 31 (estimated) No. of Industries: 1 No. of Occupations: 14 No. of Employees: 1092 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 59162 No. of Facilities: 94 (estimated) No. of Industries: 4 No. of Occupations: 7 No. of Employees: 5372 (estimated) No. of Female Employees: 446 (estimated)
Safety Information
[ Symbol ]:
GHS02, GHS07, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H228-H260-H302-H332-H400
[ Supplemental HS ]:
Contact with water liberates toxic gas.
[ Precautionary Statements ]:
P210-P223-P231 + P232-P273-P370 + P378-P422
[ Hazard Codes ]:
F:Flammable;Xn:Harmful;N:Dangerousfortheenvironment;
[ Risk Phrases ]:
R11;R20/22;R29;R50
[ Safety Phrases ]:
S61
[ RIDADR ]:
UN 1340 4.3/PG 2
[ WGK Germany ]:
3
[ RTECS ]:
TH4375000
[ Packaging Group ]:
II
[ Hazard Class ]:
4.3
[ HS Code ]:
2813900010
Customs
[ HS Code ]: 2813900010
Articles
Synthetic Metals 74(1) , 65-70, (1995)
Thiation with phosphorus pentasulfide in pyridine solution. Klingsberg E and Papa D.
J. Am. Chem. Soc. 73(10) , 4988-4989, (1951)
Phosphorus (V) sulfide. Edmondson SD and Sannigrahi M.
e-EROS Encyclopedia of Reagents for Organic Synthesis. , (2004)