Bis(triphenylphosphine)nickel(II)chloride
Names
[ CAS No. ]:
14264-16-5
[ Name ]:
Bis(triphenylphosphine)nickel(II)chloride
[Synonym ]:
EINECS 238-154-8
Bis(triphenylphosphine)nickel(II) dichloride
MFCD00009592
Bis(triphenylphosphine)nickel(II)chloride
NiCl2(PPh3)2
Dichlorobis(triphenylphosphine)nickel(II)
Nickel(II)bis(triphenylphosphine) dichloride
Phosphine, tributyl-, compd. with nickelchloride (2_1)
Chemical & Physical Properties
[ Boiling Point ]:
360ºCat 760 mmHg
[ Melting Point ]:
250ºC (dec.)
[ Molecular Formula ]:
C36H30Cl2NiP2
[ Molecular Weight ]:
654.17000
[ Flash Point ]:
181.7ºC
[ Exact Mass ]:
652.05500
[ PSA ]:
27.18000
[ LogP ]:
4.58310
[ Water Solubility ]:
insoluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- QR6170000
- CHEMICAL NAME :
- Nickel, bis(triphenylphosphine)dichloro-
- CAS REGISTRY NUMBER :
- 14264-16-5
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 8
- MOLECULAR FORMULA :
- C36-H30-Cl2-Ni-P2
- MOLECULAR WEIGHT :
- 654.21
- WISWESSER LINE NOTATION :
- 4P4&4 2 &G-NI-G
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 56 mg/kg
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03119 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992
Safety Information
[ Symbol ]:
GHS07, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H317-H350
[ Precautionary Statements ]:
P201-P280-P308 + P313
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ Hazard Codes ]:
T:Toxic;
[ Risk Phrases ]:
R20/21/22;R34;R45
[ Safety Phrases ]:
S26-S36/37/39-S45-S53
[ RIDADR ]:
UN2923
[ WGK Germany ]:
3
[ RTECS ]:
QR6170000
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1(b)
[ HS Code ]:
29310095
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 29310095