<Suppliers Price>

Bis(triphenylphosphine)nickel(II)chloride

Names

[ CAS No. ]:
14264-16-5

[ Name ]:
Bis(triphenylphosphine)nickel(II)chloride

[Synonym ]:
EINECS 238-154-8
Bis(triphenylphosphine)nickel(II) dichloride
MFCD00009592
Bis(triphenylphosphine)nickel(II)chloride
NiCl2(PPh3)2
Dichlorobis(triphenylphosphine)nickel(II)
Nickel(II)bis(triphenylphosphine) dichloride
Phosphine, tributyl-, compd. with nickelchloride (2_1)

Chemical & Physical Properties

[ Boiling Point ]:
360ºCat 760 mmHg

[ Melting Point ]:
250ºC (dec.)

[ Molecular Formula ]:
C36H30Cl2NiP2

[ Molecular Weight ]:
654.17000

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
652.05500

[ PSA ]:
27.18000

[ LogP ]:
4.58310

[ Water Solubility ]:
insoluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QR6170000
CHEMICAL NAME :
Nickel, bis(triphenylphosphine)dichloro-
CAS REGISTRY NUMBER :
14264-16-5
LAST UPDATED :
199701
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C36-H30-Cl2-Ni-P2
MOLECULAR WEIGHT :
654.21
WISWESSER LINE NOTATION :
4P4&4 2 &G-NI-G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03119 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H317-H350

[ Precautionary Statements ]:
P201-P280-P308 + P313

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R20/21/22;R34;R45

[ Safety Phrases ]:
S26-S36/37/39-S45-S53

[ RIDADR ]:
UN2923

[ WGK Germany ]:
3

[ RTECS ]:
QR6170000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
29310095

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 29310095


Related Compounds