3,3'-Diphenyl-2,2'-binaphthalene-1,1'-diol
Names
[ CAS No. ]:
147702-13-4
[ Name ]:
3,3'-Diphenyl-2,2'-binaphthalene-1,1'-diol
[Synonym ]:
3,3'-diphenyl-<2,2'-binaphthalene>-1,1'-diol
MFCD08459338
3,3'-Diphenyl-2,2'-binaphthalene-1,1'-diol
[2,2'-Binaphthalene]-1,1'-diol, 3,3'-diphenyl-
Chemical & Physical Properties
[ Density]:
1.3±0.1 g/cm3
[ Boiling Point ]:
580.1±50.0 °C at 760 mmHg
[ Melting Point ]:
200-204ºC
[ Molecular Formula ]:
C32H22O2
[ Molecular Weight ]:
438.516
[ Flash Point ]:
251.7±24.7 °C
[ Exact Mass ]:
438.161987
[ PSA ]:
40.46000
[ LogP ]:
6.94
[ Vapour Pressure ]:
0.0±1.7 mmHg at 25°C
[ Index of Refraction ]:
1.727
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H315-H318-H335-H413
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R37/38
[ Safety Phrases ]:
S26
[ RIDADR ]:
NONH for all modes of transport
Articles
Org. Lett. 7 , 367, (2005)
[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carbo...
Highly enantioselective deracemization of linear and vaulted biaryl ligands.Org. Lett. 5 , 1813, (2003)
[reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ...
Bao. J. et al.J. Am. Chem. Soc. 118 , 3392, (1996)