2-Amino-3-bromo-5-picoline

Names

[ Name ]:
2-Amino-3-bromo-5-picoline

[Synonym ]:
2-Pyridinamine, 3-bromo-5-methyl-
3-Bromo-5-methylpyridin-2-ylamine
6-Amino-5-bromo-3-picoline
T6NJ BZ CE E1
MFCD00068231
3-Bromo-5-Methylpyridin-2-Amine
2-Amino-3-bromo-5-picoline
3-Bromo-5-methyl-2-pyridinamine
2-Amino-3-bromo-5-methylpyridine

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
252.3±35.0 °C at 760 mmHg

[ Melting Point ]:
73-76 °C(lit.)

[ Molecular Formula ]:
C₆H₇BrN₂

[ Molecular Weight ]:
187.037

[ Flash Point ]:
106.4±25.9 °C

[ Exact Mass ]:
185.979248

[ PSA ]:
38.91000

[ LogP ]:
2.59

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.617

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Some 2, 5-and 5, 6-Dihalonicotinic acids and their precursors Setliff FL.

J. Chem. Eng. Data 15.41 , 590-591, (1970)

Synthesis of medium ring nitrogen heterocycles via a tandem copper-catalyzed CN bond formation-Ring-expansion process Klapars, Artis, et al.

J. Am. Chem. Soc. 126.11 , 3529-3533, (2004)

Phosphonylation of 2-Amino-and 2-Amido-3-bromopyridines and 2-Amino-3-chloroquinoxalines with Triethyl Phosphite Adam M, et al.

European J. Org. Chem. 2009.27 , 4655-4665, (2009)