1,3-Dimethoxy-4-bromobenzene

Names

[ Name ]:
1,3-Dimethoxy-4-bromobenzene

[Synonym ]:
EINECS 241-717-0
2,4-dimethoxy-1-bromobenzene
2,4-DIMETHOXYBROMOBENZENE
1,3-Dmethoxy-4-bromobenzene
4-BROMORESOCINOL DIMETHYL ETHER
3-Methoxy-4-bromoanisole
1,3-Dimethoxy-4-bromobenzene
Benzene, 1-bromo-2,4-dimethoxy-
MFCD00009844
2,4-Dimethoxyphenyl bromide
2,4-diMethoxylbroMophenol
1-bromo-2,4-dimethoxy-benzene
1-Bromo-2,4-dimethox
1-Bromo-2,4-dimethoxybenzene
4-Bromo-1,3-dimethoxybenzene

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
281.7±0.0 °C at 760 mmHg

[ Melting Point ]:
25-26 °C(lit.)

[ Molecular Formula ]:
C₈H₉BrO₂

[ Molecular Weight ]:
217.060

[ Flash Point ]:
110.5±17.3 °C

[ Exact Mass ]:
215.978592

[ PSA ]:
18.46000

[ LogP ]:
2.76

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.528

[ Storage condition ]:
0-6°C

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Synthesis of 2,3-disubstituted benzo[b]furans by the palladium-catalyzed coupling of o-iodoanisoles and terminal alkynes, followed by electrophilic cyclization.

J. Org. Chem. 70(25) , 10292-6, (2005)

[reaction: see text] 2,3-Disubstituted benzo[b]furans are readily prepared under very mild reaction conditions by the palladium/copper-catalyzed cross-coupling of various o-iodoanisoles and terminal a...

Selective lithiation and crystal structures of G1-carbosilane dendrimers with dimethoxybenzene functionalities. Harder S, et al.

J. Organomet. Chem. 689(7) , 1095-1101, (2004)