Phenyl 2-pyridyl ketoxime
Names
[ CAS No. ]:
1826-28-4
[ Name ]:
Phenyl 2-pyridyl ketoxime
[Synonym ]:
PPKO
MFCD00006310
2-Benzoylpyridiineketoxime
Phenylpyridylketoxime
PHENYL-A-PYRIDYL KETOXIME
EINECS 217-374-8
2-Benzoylpyridine oxime
phenyl-pyridine-2-yl-methanone oxime
phenyl-2-pyridylketone oxime
2-pyridyl phenyl ketone oxime
2-BENZOYLPYRIDINE KETOXIME
Chemical & Physical Properties
[ Density]:
1.13 g/cm3
[ Boiling Point ]:
364.703ºC at 760 mmHg
[ Melting Point ]:
154-156 °C(lit.)
[ Molecular Formula ]:
C12H10N2O
[ Molecular Weight ]:
198.22100
[ Exact Mass ]:
198.07900
[ PSA ]:
45.48000
[ LogP ]:
2.30820
[ Vapour Pressure ]:
0mmHg at 25°C
[ Index of Refraction ]:
1.596
[ Water Solubility ]:
insoluble
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301-H315-H318-H335
[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36/37/39-S45-S37/39
[ RIDADR ]:
UN 2811 6.1/PG 3
[ WGK Germany ]:
3
[ HS Code ]:
2933399090
Synthetic Route
Customs
[ HS Code ]: 2933399090
[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
Dalton Trans. 39(3) , 765-75, (2010)
Interaction of phenyl 2-pyridyl ketoxime (PhPyCNO)/X(-)"blends" (X(-) = OH(-), Cl(-), ClO(4)(-), 2,4-D) (2,4-DH = 2,4-dichlorophenoxyacetic acid) with copper perchlorate has yielded trinuclear cluster...
Potentiometric study of binary complexes of methyl 2-pyridyl ketone oxime, phenyl 2-pyridyl ketone oxime and diacetyl monooxime with some transition and heavy metal ions in aqueous solution.Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 71(2) , 655-62, (2008)
The complexation reaction between some oximes including methyl-2-pyridylketone oxime (MPKO), phenyl-2-pyridylketone oxime (PPKO) and diacetyl monooxime (DMO) with some transition and heavy metal ions ...
Mononuclear versus dinuclear complex formation in nickel(II) sulfate/phenyl(2-pyridyl)ketone oxime chemistry depending on the ligand to metal reaction ratio: synthetic, spectral and structural studies.Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 70(4) , 718-28, (2008)
The reactions of phenyl(2-pyridyl)ketone oxime (py)C(ph)NOH, with nickel(II) sulfate hexahydrate under reflux, in the absence of an external base, have been investigated. The reaction of NiSO4 x 6H2O ...