Trimethylsilyl bromoacetate
Names
[ CAS No. ]:
18291-80-0
[ Name ]:
Trimethylsilyl bromoacetate
[Synonym ]:
ACETIC ACID, BROMO-, TRIMETHYLSILYL ESTER
Acetic acid,bromo-,trimethylsilyl ester
Trimethylsilylbromacetat
EINECS 242-165-3
Trimethylsilyl bromoacetate
Acetic acid, 2-bromo-, trimethylsilyl ester
Bromoacetic Acid Trimethylsilyl Ester
Bromessigsaeure-trimethylsilylester
MFCD00000187
Chemical & Physical Properties
[ Density]:
1.3±0.1 g/cm3
[ Boiling Point ]:
173.7±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C5H11BrO2Si
[ Molecular Weight ]:
211.129
[ Flash Point ]:
39.6±22.6 °C
[ Exact Mass ]:
209.971161
[ PSA ]:
26.30000
[ LogP ]:
1.93
[ Vapour density ]:
>1 (vs air)
[ Vapour Pressure ]:
1.3±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.444
[ Storage condition ]:
Flammables area
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H226-H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C
[ Risk Phrases ]:
R10
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
UN 2920 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
8
[ HS Code ]:
2931900090
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Bioorg. Med. Chem. 10(7) , 2397-414, (2002)
A series of Taxol derivatives tethered at C2' and C-7 to glutamate and folate have been synthesized for evaluation as prodrugs which release Taxol via hydrolytic lability of their alpha-alkoxy and alp...
Copper and palladium complexes with N-heterocyclic carbene ligands functionalised with carboxylate groups. Danopoulos AA, et al.J. Organomet. Chem. 693(21) , 3369-74, (2008)
The [1, 2]-thio-Wittig rearrangement: evidence for a radical mechanism and its suppression. Bertolli P, et al.
Tetrahedron Lett. 47(45) , 7939-42, (2006)