Benzene,[(bromomethyl)sulfonyl]-

Names

[ CAS No. ]:
19169-90-5

[ Name ]:
Benzene,[(bromomethyl)sulfonyl]-

[Synonym ]:
4-bromo-methylsulfonylbenzene
Brom-phenylsulfon-methan
Phenylsulfon-methylbromid
Brommethyl-phenyl-sulfon
MFCD00034033
ethyl bromoacetate
Bromomethyl phenyl sulfone

Chemical & Physical Properties

[ Density]:
1.628g/cm3

[ Boiling Point ]:
351.3ºC at 760mmHg

[ Melting Point ]:
51-53ºC(lit.)

[ Molecular Formula ]:
C₇H₇BrO₂S

[ Molecular Weight ]:
235.09800

[ Flash Point ]:
166.3ºC

[ Exact Mass ]:
233.93500

[ PSA ]:
42.52000

[ LogP ]:
2.89350

[ Vapour Pressure ]:
8.38E-05mmHg at 25°C

[ Index of Refraction ]:
1.578

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2904909090

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Nucleophilic displacements alpha to sulfonyl groupings. Bordwell FG and Jarvis BB.

J. Org. Chem. 33(3) , 1182-85, (1968)

Base-induced disproportionation of halomethyl phenyl sulfones to methyl and dihalomethyl phenyl sulfones. Galvagni M, et al.

J. Org. Chem. 55(14) , 4454-56, (1990)