Dichloro(3-methyl-2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)
Names
[ CAS No. ]:
194659-03-5
[ Name ]:
Dichloro(3-methyl-2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)
[Synonym ]:
RuCl2(=CHCH=CMe2)(PCy3)2
dichloro(3-methyl-1,2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)
Grubbs Catalyst 801
(CH3)2C=CHCH=Ru(PCy3)2Cl2
Bis(tricyclohexylphosphine)isopentenylidene ruthenium dichloride
MFCD04039970
Dichloro(3-methyl-2-buten-1-ylidene)ruthenium - tricyclohexylphosphine (1:2)
3-ME-2-BUTENYLIDENEBIS(TRICYCLOHEXYLPHOSPHINE)DICHLORORUTHE.
Dichloro(3-methyl-2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)
ruthenium(II) dichloro(3-methyl-1,2-butenylidene)bis(tricyclohexylphosphine)
Phosphine, tricyclohexyl-, compd. with dichloro(3-methyl-2-buten-1-ylidene)ruthenium (2:1)
Chemical & Physical Properties
[ Boiling Point ]:
383.4±0.0 °C at 760 mmHg
[ Melting Point ]:
160-165ºC(lit.)
[ Molecular Formula ]:
C41H74Cl2P2Ru
[ Molecular Weight ]:
800.950
[ Flash Point ]:
195.6±0.0 °C
[ Exact Mass ]:
800.369019
[ PSA ]:
27.18000
[ LogP ]:
7.00
[ Vapour Pressure ]:
0.0±0.0 mmHg at 25°C
[ Storage condition ]:
2-8°C
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H228
[ Precautionary Statements ]:
P210
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
F+
[ Safety Phrases ]:
22-24/25
[ RIDADR ]:
UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
[ WGK Germany ]:
3
Articles
Aldrichimica Acta 40th ed.,, 45, (2007)
Vougioukalakis, G. C.; Grubbs, R. H.
Chem. Rev. 110th ed.,, 1746, (2010)
Grubbs, R. H.
Tetrahedron 60th ed.,, 7117, (2004)