(3AR,8AR)-N,N,2,2-TETRAMETHYL-4,4,8,8-TETRAPHENYLTETRAHYDRO-[1,3]DIOXOLO[4,5-E][1,3,2]DIOXAPHOSPHEPIN-6-AMINE

Names

[ CAS No. ]:
213843-90-4

[ Name ]:
(3AR,8AR)-N,N,2,2-TETRAMETHYL-4,4,8,8-TETRAPHENYLTETRAHYDRO-[1,3]DIOXOLO[4,5-E][1,3,2]DIOXAPHOSPHEPIN-6-AMINE

[Synonym ]:
MFCD04117685

Chemical & Physical Properties

[ Boiling Point ]:
569.804ºC at 760 mmHg

[ Melting Point ]:
218-221ºC

[ Molecular Formula ]:
C₃₃H₃₄NO₄P

[ Molecular Weight ]:
539.60100

[ Flash Point ]:
298.407ºC

[ Exact Mass ]:
539.22300

[ PSA ]:
53.75000

[ LogP ]:
7.22940

[ Vapour Pressure ]:
0mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Articles

Copper-catalyzed asymmetric conjugate addition of diethylzinc to alpha,beta-unsaturated imines derived from alpha-aminoacids. Enantioselective synthesis of gamma-substituted alpha-dehydroaminoesters.

Org. Lett. 8 , 5405, (2006)

[Structure: see text] A highly enantioselective synthesis of alpha-dehydroaminoacids with a stereogenic center in the gamma position through copper-catalyzed asymmetric conjugate addition of diethylzi...

Tetrahedron Lett. 48 , 3305, (2007)