Triallate

Names

[ Name ]:
Triallate

[Synonym ]:
S-(2,3,3-trichloro-2-propen-1-yl) N,N-bis(1-methylethyl)carbamothioate
s-2,3,3-trichloroallyl diisopropylthiocarbamate
S-(2,3,3-trichloroprop-2-en-1-yl) dipropan-2-ylcarbamothioate
Triamyl
Diisopropylthiocarbamate de S-(2,3,3-trichloro-2-propèn-1-yle)
N,N-diisopropylthiocarbamic acid 2,3,3-trichloroallyl ester
S-(2,3,3-trichloroprop-2-en-1-yl) di(propan-2-yl)carbamothioate
S-(2,3,3-trichloroprop-2-enyl) N,N-di(propan-2-yl)carbamothioate
S-(2,3,3-Trichloroprop-2-en-1-yl) diisopropylcarbamothioate
Triallate
Bis(1-methylethyl)carbamothioic acid S-(2,3,3-trichloro-2-propenyl) ester
S-2,3,3-trichloroallyl diisopropyl(thiocarbamate)
MFCD00078730
S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate (9CI)
S-(2,3,3-Trichloroallyl) diisopropylthiocarbamate (8CI)
Caswell No. 870A
Far-Go
EINECS 218-962-7
S-(2,3,3-Trichlorprop-2-en-1-yl)-diisopropylthiocarbamat
Carbamothioic acid, N,N-bis(1-methylethyl)-, S-(2,3,3-trichloro-2-propen-1-yl) ester
S-(2,3,3-Trichlor-2-propen-1-yl)-diisopropylthiocarbamat
S-(2,3,3-trichloroprop-2-en-1-yl) diisopropylthiocarbamate
S-(2,3,3-Trichloro-2-propen-1-yl) diisopropylcarbamothioate
Carbamothioic acid, bis(1-methylethyl)-, S-(2,3,3-trichloro-2-propenyl) ester
Triallat
Avadex BW
S-(2,3,3-trichloroprop-2-en-1-yl) bis(1-methylethyl)thiocarbamate
S-2,3,3-trichloroallyl diisopropyl thiocarbamate
Dipthal

Biological Activity

[Description]:

Triallate is a selective preemergence herbicide for the control of wild oats in barley, spring wheat, Durum wheat, winter wheat, and sugar beets. Triallate inhibits fatty acid elongation and surface lipid (wax) biosynthesis[1][2].

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

[References]

[1]. Charles E Healy, et al. A Review of the Genotoxicity of Triallate. Int J Toxicol. May-Jun 2003;22(3):233-51.

[2]. Roberto Busi, et al. Cross-resistance to Prosulfocarb and Triallate in Pyroxasulfone-Resistant Lolium Rigidum. Pest Manag Sci. 2013 Dec;69(12):1379-84.

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
322.1±52.0 °C at 760 mmHg

[ Melting Point ]:
29-30°C

[ Molecular Formula ]:
C₁₀H₁₆Cl₃NOS

[ Molecular Weight ]:
304.664

[ Flash Point ]:
148.6±30.7 °C

[ Exact Mass ]:
303.001831

[ PSA ]:
45.61000

[ LogP ]:
6.18

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.532

[ Water Solubility ]:
4.0 g/mL

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EZ8575000

CHEMICAL NAME :: Carbamic acid, diisopropylthio-, S-(2,3,3-trichloroallyl) ester

CAS REGISTRY NUMBER :: 2303-17-5

LAST UPDATED :: 199701

DATA ITEMS CITED :: 25

MOLECULAR FORMULA :: C10-H16-Cl3-N-O-S

MOLECULAR WEIGHT :: 304.68

WISWESSER LINE NOTATION :: GYGUYG1SVNY1&1&Y1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1471 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 930 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - excitement Behavioral - muscle contraction or spasticity

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 832 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: >20 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 400 mg/m3/4H

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal)

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2225 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 2251 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 17493 mg/kg/17W-I

TOXIC EFFECTS :: Related to Chronic Data - death

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 40 mg/m3/4H/17W-I

TOXIC EFFECTS :: Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 20 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 85,45,1981 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Symbol ]:

GHS07, GHS08, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H317-H373-H410

[ Precautionary Statements ]:
P273-P280-P501

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;

[ Risk Phrases ]:
R22;R43;R48/22;R50/53

[ Safety Phrases ]:
S24-S37-S60-S61-S36-S26-S16

[ RIDADR ]:
UN 3077

[ RTECS ]:
EZ8575000

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
2930200013

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2930200013

[ Summary ]:
2930200013 (z)-s-(2,3-dichloroallyl) diisopropylcarbamothioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

Articles

Carry-over of dinitramine, triallate, and trifluralin to the following spring in soils treated at different times during the fall.

Bull. Environ. Contam. Toxicol. 29(4) , 483-6, (1982)

Volatilization modeling of two herbicides from soil in a wind tunnel experiment under varying humidity conditions.

Environ. Sci. Technol. 46(22) , 12527-33, (2012)

Volatilization of pesticides from the bare soil surface is drastically reduced when the soil is under dry conditions (i.e., water content lower than the permanent wilting point). This effect is caused...

Body mass index and bromoxynil exposure in a sample of rural residents during spring herbicide application.

J. Toxicol. Environ. Health A 67(17) , 1321-52, (2004)

Bromoxynil (3,5-dibromo-4-hydroxybenzonitrile), a phenolic herbicide, is widely used in production of cereals and other crops. Little is known, however, about bromoxynil exposure in humans. Results of...