Trimethylsilyl acetate
Names
[ CAS No. ]:
2345-38-2
[ Name ]:
Trimethylsilyl acetate
[Synonym ]:
MFCD00042651
Trimethylsilylacetic acid
trimethylsilanyl-acetic acid
Silanol, 1,1,1-trimethyl-, acetate
2-(Trimethylsilyl)ethansaeure
(trimethylsilyl)-aceticaci
Acetic acid, trimethylsilyl ester
Silanol, trimethyl-, acetate
2-(Trimethylsilyl)acetic acid
EINECS 219-067-4
Trimethylsilyl acetate
me3SiCH2cox
Chemical & Physical Properties
[ Density]:
0.9±0.1 g/cm3
[ Boiling Point ]:
107.5±0.0 °C at 760 mmHg
[ Melting Point ]:
39-42 °C(lit.)
[ Molecular Formula ]:
C5H12O2Si
[ Molecular Weight ]:
132.233
[ Flash Point ]:
4.4±0.0 °C
[ Exact Mass ]:
132.060654
[ PSA ]:
37.30000
[ LogP ]:
1.24
[ Vapour Pressure ]:
27.0±0.2 mmHg at 25°C
[ Index of Refraction ]:
1.391
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
UN3261
[ WGK Germany ]:
2
[ RTECS ]:
AK0843500
[ Packaging Group ]:
III
[ Hazard Class ]:
8
[ HS Code ]:
2931900090
Synthetic Route
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
J. Chem. Soc. Chem. Commun. , 537, (1975)
D.H. Lucast, J. Wemple
Tetrahedron Lett. , 1103, (1977)
G.A. Olah et al.
Synthesis , 568, (1989)