Grubbs Catalyst 2nd Generation
Names
[ CAS No. ]:
246047-72-3
[ Name ]:
Grubbs Catalyst 2nd Generation
[Synonym ]:
GRUBB'S SECOND GENERATION CATALYST
(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium
[1,3-Bis-(2,4,6-trimethylpheny
MFCD03453237
Grubb's 2nd generation catalyst
Benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium - tricyclohexylphosphine (1:1)
Phosphine, tricyclohexyl-, compd. with [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)ruthenium (1:1)
Grubbs catalyst,2nd Generation
Grubbs 2
Chemical & Physical Properties
[ Melting Point ]:
143-149ºC
[ Molecular Formula ]:
C46H65Cl2N2PRu
[ Molecular Weight ]:
848.971
[ Exact Mass ]:
848.330627
[ PSA ]:
20.07000
[ LogP ]:
13.86190
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H228
[ Precautionary Statements ]:
P210
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
F
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
26-36/37/39
[ RIDADR ]:
1325
[ WGK Germany ]:
3
[ Packaging Group ]:
Ⅱ
Precursor & DownStream
Precursor
DownStream
Articles
Chem. Rev. 110 , 1746, (2010)
Olefin Metathesis and Beyond A list of abbreviations can be found at the end of this article.
Angew. Chem. Int. Ed. Engl. 39 , 3012, (2000)
The advent of well-defined catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups has revolutionized the field. The past decad...
Highly Efficient Ring-Opening Metathesis Polymerization (ROMP) Using New Ruthenium Catalysts Containing N-Heterocyclic Carbene Ligands C.B. is grateful to the National Science Foundation for a pre-doctoral fellowship. The authors thank Dr. Matthias Scholl for providing catalysts 4 a and 4 c.Angew. Chem. Int. Ed. Engl. 39 , 2903, (2000)