1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE

Names

[ Name ]:
1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE

[Synonym ]:
SIPr.HCl
MFCD07369796
1H-Imidazolium, 1,3-bis[2,6-bis(1-methylethyl)phenyl]-4,5-dihydro-, chloride (1:1)
1,3-Bis(2,6-diisopropylphenyl)iMidazoliniuM Chloride
1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazol-3-ium chloride
1,3-Bis(2,6-diisopropylphenyl)imidazolidinium chloride

Chemical & Physical Properties

[ Melting Point ]:
289-293ºC(lit.)

[ Molecular Formula ]:
C₂₇H₃₉ClN₂

[ Molecular Weight ]:
427.065

[ Exact Mass ]:
426.280182

[ PSA ]:
6.25000

[ LogP ]:
7.39650

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

Articles

Palladium-(N-heterocyclic carbene) hydrogenation catalysts.

Angew. Chem. Int. Ed. Engl. 44 , 2026, (2005)

NHC-catalyzed ring expansion of oxacycloalkane-2-carboxaldehydes: a versatile synthesis of lactones.

Org. Lett. 11 , 891, (2009)

Imidazolinium-derived carbenes catalyze the ring-expansion lactonization of oxacycloalkane-2-carboxaldehydes. A variety of functionalized five-, six-, and seven-membered lactones can be formed efficie...

Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions.

J. Org. Chem. 4 , 2079, (2002)

[reaction: see text] Catalyst formed from N,N-bis(2,6-diisopropylphenyl)dihydroimidazolium chloride and palladium(II) acetate (2 mol %) was used, without added base, to efficiently produce Heck couple...