(S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI&
Names
[ CAS No. ]:
274674-23-6
[ Name ]:
(S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI&
[Synonym ]:
I11-1035
(S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI&Pyrrolidine,2-(fluorodiphenylmethyl)-,(2S)
(S)-2-[(fluoro)(diphenyl)methyl]pyrrolidine
MFCD03093547
Chemical & Physical Properties
[ Molecular Formula ]:
C17H18FN
[ Molecular Weight ]:
255.33000
[ Exact Mass ]:
255.14200
[ PSA ]:
12.03000
[ LogP ]:
3.98050
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
26-36
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Chemistry 36th ed., 18 , 11334-11342, (2012)
The fluorine-iminium ion gauche effect is triggered upon union of a secondary β-fluoroamine and an α,β-unsaturated aldehyde, providing a useful strategy for controlling the molecular topology of inter...
Sparr, C.; et al.Angew. Chem. Int. Ed. Engl. 121 , 3065-3068, (2009)
Zimmer, L. E.; et al.
Angew. Chem. Int. Ed. Engl. 123 , 12062-12074, (2011)