2,3,4,6-Tetra-O-acetyl-alpha-D-galactopyranosyl bromide
Names
[ CAS No. ]:
3068-32-4
[ Name ]:
2,3,4,6-Tetra-O-acetyl-alpha-D-galactopyranosyl bromide
[Synonym ]:
A-D-GALACTOPYRANOSYL BROMIDE
acetobromo-D-galactose
(2R,3S,4S,5R,6R)-2-(acetoxymethyl)-6-bromotetrahydro-2H-pyran-3,4,5-triyl triacetate
D-A-TETRAACETOBROMOGALACTOSE
2,3,4,6-Tetra-O-acetyl-a-D-galactopyranosyl bromide
2,3,4,6-Tetra-O-acetyl-alpha-D-galactopyranosyl bromide
Acetobromo-α-D-galactose
2,3,4,6-Tetra-O-acetyl-α-D-galactopyranosyl bromide
tetraacetylbromogalactose
EINECS 221-324-0
α-D-Galactopyranosyl bromide, tetraacetate
MFCD00063686
acetobromogalactose
ACETOBROMO-A-D-GALACTOSE
acetic acid 4,5-diacetoxy-6-acetoxymethyl-2-bromotetrahydropyran-3-yl ester
Chemical & Physical Properties
[ Density]:
1.5±0.1 g/cm3
[ Boiling Point ]:
412.0±45.0 °C at 760 mmHg
[ Melting Point ]:
83-85 °C
[ Molecular Formula ]:
C14H19BrO9
[ Molecular Weight ]:
411.199
[ Flash Point ]:
203.0±28.7 °C
[ Exact Mass ]:
410.021240
[ PSA ]:
114.43000
[ LogP ]:
2.05
[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C
[ Index of Refraction ]:
1.503
[ Storage condition ]:
-20°C
[ Water Solubility ]:
Sparingly soluble
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
Precursor & DownStream
Precursor
DownStream
Articles
Carbohydr. Res. 341 , 1077-1080, (2006)
The synthesis of oligosaccharide fragments of the O-specific polysaccharide of Vibrio cholerae O139 containing a 4,6-cyclic phosphate galactose residue linked to GlcNAc is described. 8-Azido-3,6-dioxa...
Glycosylation of l,4:3,6-dianhydro-D-glucitol (isosorbide).Carbohydr. Res. 339 , 2433-2440, (2004)
Condensation of 2,3,4,6-tetra-O-acetyl-alpha-D-glucopyranosyl-, 2,3,4-tri-O-acetyl-alpha-D-xylopyranosyl- and of 2,3,4,6-tetra-O-acetyl-alpha-D-galactopyranosyl bromides with l,4:3,6-dianhydro-D-gluci...
A new approach for the N- and S-galactosylation of 5-arylidene-2-thioxo-4-thiazolidinonesCarbohydr. Res. 346 , 2831-2837, (2011)
N- and S-galactosylation was carried out via the reaction of 5-((Z)-arylidene)-2-thioxo-4-thiazolidinones with 2,3,4,6-tetra-O-acetyl-α-d-galactopyranosyl bromide under alkaline conditions or under si...