Dichlorobis(di-|tert|-butylphenylphosphine)palladium(II)

Names

[ Name ]:
Dichlorobis(di-|tert|-butylphenylphosphine)palladium(II)

[Synonym ]:
Bis(2-methyl-2-propanyl)(phenyl)phosphine - dichloropalladium (2:1)
PdCl2[P(t-Bu)2Ph]2
bis[(di-tert-butylphenylphosphine)]palladium dichloride
bis[di-tert-butyl(phenyl)phosphane]dichloropalladium
Dichlorobis(di-tert-butylphenylphosphine)palladiuM(II),Pd
dichlorobis(phenyldi-tert-butylphosphine)palladium
trans-Dichlorobis(di-tert-butylphenylphosphine)palladium(II)
palladium(II)bis(di-tert-butylphenylphosphine) dichloride

Chemical & Physical Properties

[ Molecular Formula ]:
C₂₈H₄₆Cl₂P₂Pd

[ Molecular Weight ]:
621.938

[ Exact Mass ]:
620.148682

[ PSA ]:
27.18000

[ LogP ]:
10.16060

[ Storage condition ]:
2~8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Hazard Codes ]:
Xn

[ Safety Phrases ]:
36/37/39

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

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Precursor & DownStream

Precursor

DownStream

Articles

New air-stable catalysts for general and efficient suzuki-miyaura cross-coupling reactions of heteroaryl chlorides.

Org. Lett. 8 , 1787, (2006)

[reaction: see text] New air-stable PdCl(2){P(t)Bu(2)(p-R-Ph)}(2) (R = H, NMe(2), CF(3),) complexes represent simple, general, and efficient catalysts for the Suzuki-Miyaura cross-coupling reactions o...

New catalysts for Suzuki-Miyaura coupling reactions of heteroatom-substituted heteroaryl chlorides.

J. Org. Chem. 72 , 5104, (2007)

The new air-stable PdCl2[PR2(Ph-R')]2 complexes, readily prepared from commercial reagents, exhibit unique efficiency as catalysts for the Suzuki-Miyaura coupling reactions of a variety of heteroatom-...

Palladium(0)-catalyzed cross-coupling of potassium (Z)-2-chloroalk-1-enyl trifluoroborates: a chemo- and stereoselective access to (Z)-chloroolefins and trisubstituted alkenes.

Chemistry 15 , 5793, (2009)

We describe the preparation of a series of new potassium trifluoroborates 1 and the study of their behaviour in a Pd(0)-catalyzed cross-coupling reaction. We found that compounds 1 are endowed with or...