Butocarboxim

Names

[ Name ]:
Butocarboxim

[Synonym ]:
3-Methylsulfanyl-butan-2-one O-methylcarbamoyl-oxime
4-Oxa-8-thia-2,5-diazanon-5-en-3-one, 6,7-dimethyl-
DRAWIN
(5Ξ)-6,7-dimethyl-4-oxa-8-thia-2,5-diazanon-5-en-3-one
Afiline
Drawin 50
Co 755-d3
EINECS 252-139-3
6,7-Dimethyl-4-oxa-8-thia-2,5-diazanon-5-en-3-one
MFCD00055326
Butocarboxim
3-(methylthio)-2-butanone O-[(methylamino)carbonyl]oxime
Butocarboxime
(EZ)-3-(methylthio)butanone O-methylcarbamoyloxime
Drawin 755
CO 755

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Molecular Formula ]:
C₇H₁₄N₂O₂S

[ Molecular Weight ]:
190.263

[ Exact Mass ]:
190.077591

[ PSA ]:
75.99000

[ LogP ]:
1.49

[ Index of Refraction ]:
1.505

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EL9215000

CHEMICAL NAME :: 2-Butanone, 3-(methylthio)-, O-(N-methylcarbamoyl)oxime

CAS REGISTRY NUMBER :: 34681-10-2

LAST UPDATED :: 199612

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C7-H14-N2-O2-S

MOLECULAR WEIGHT :: 190.29

WISWESSER LINE NOTATION :: 1SY1&Y1&UNOVM1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 153 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976 Volume(issue)/page/year: -,-,1971/1976

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1 gm/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,109,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 188 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,109,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 360 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C55,1991

Safety Information

[ Symbol ]:

GHS02, GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H301-H311-H319-H331-H410

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P305 + P351 + P338-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T: Toxic;N: Dangerous for the environment;

[ Risk Phrases ]:
10-23/24/25-36-50/53

[ Safety Phrases ]:
S45;S60;S61;S36/S37

[ RIDADR ]:
UN 2757

[ RTECS ]:
EL9215000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2930909051

Customs

[ HS Code ]: 2930909051

[ Summary ]:
2930909051 (e)-3-(methylthio)butan-2-one o-methylcarbamoyl oxime。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

Articles

Direct gas chromatographic determination of the two isomeric insecticides, aldicarb and butocarboxime and their toxic metabolites: application to residue analysis in crops and leaves.

Z. Lebensm. Unters. Forsch. 180(2) , 96-100, (1985)

A gas-chromatographic method is described for determination of residues of butocarboxime (Drawin), its structural isomer aldicarb (Temik), and their toxic sulfoxide and sulfone metabolites. These comp...

Monitoring butocarboxim resistance of the woolly whitefly (Homoptera: Aleyrodidae) in citrus from Valencia, Spain.

J. Econ. Entomol. 94(6) , 1558-63, (2001)

Glass vials coated internally with an insecticide were used as a resistance monitoring technique for testing field populations of the woolly whitefly, Aleurothrixus floccosus (Maskell), collected from...