(1S)-(-)-Camphanic chloride

Names

[ Name ]:
(1S)-(-)-Camphanic chloride

[Synonym ]:
2-Oxabicyclo[2.2.1]heptane-1-carbonyl chloride, 4,7,7-trimethyl-3-oxo-, (1S,4R)-
(1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride
MFCD00135626
(1S)-(-)-Camphanic chloride
2-Oxabicyclo[2.2.1]heptane-1-carbonyl chloride, 4,7,7-trimethyl-3-oxo-
(-)-Camphanic Chloride
EINECS 254-552-4
4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
299.5±23.0 °C at 760 mmHg

[ Melting Point ]:
71-73 °C(lit.)

[ Molecular Formula ]:
C₁₀H₁₃ClO₃

[ Molecular Weight ]:
216.661

[ Flash Point ]:
125.0±21.6 °C

[ Exact Mass ]:
216.055328

[ PSA ]:
43.37000

[ LogP ]:
0.96

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.520

[ Water Solubility ]:
decomposes

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R29;R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S8

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2916209090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2916209090

[ Summary ]:
2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

Articles

High-performance liquid chromatographic determination of (R)-and (S)-proxyphylline in human plasma.

J. Chromatogr. A. 491(2) , 355-66, (1989)

A reversed-phase high-performance liquid chromatographic assay has been developed for determination of (R)-(--)-and (S)-(+)-proxyphylline in human plasma. The procedure is based on liquid-solid extrac...

The determination of the absolute configurations of diastereomers of (S)-camphanoyl 3-hydroxy-5-oxohexanoic acid derivatives by X-ray crystallography.

Angew. Chem. Int. Ed. Engl. 41(7) , 1198-202, (2002)

A. Haag et al.

Helv. Chim. Acta 63 , 10, (1980)