6-methyl-2,2'-bipyridine
Names
[ CAS No. ]:
56100-22-2
[ Name ]:
6-methyl-2,2'-bipyridine
[Synonym ]:
6-Methyl-2,2'dipyridine
6-methyl-2,2'-bipyridine
6-methyl-2-(2-pyridyl)pyridine
6-Methyl-2,2'-dipyridyl
MFCD02093688
2,2'-bipyridine,6-methyl
6-Methyl-[2,2']bipyridinyl
2-methyl-6-(pyridin-2-yl)pyridine
Chemical & Physical Properties
[ Density]:
1.09 g/mL at 25ºC(lit.)
[ Boiling Point ]:
117-119ºC0.1 mm Hg(lit.)
[ Molecular Formula ]:
C11H10N2
[ Molecular Weight ]:
170.21000
[ Flash Point ]:
>230 °F
[ Exact Mass ]:
170.08400
[ PSA ]:
25.78000
[ LogP ]:
2.45200
[ Index of Refraction ]:
n20/D 1.607(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
26-36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2933399090
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2933399090
[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
J. Org. Chem. 79(24) , 12018-32, (2014)
A fast and efficient protocol for the palladium(II)-catalyzed production of aryl ketones from sodium arylsulfinates and various organic nitriles under controlled microwave irradiation has been develop...
Chemical Constitution and Activity of Bipyridylium Herbicides. XII. Diquaternary Salts of 6-Methyl-2, 2'-bipyridyl and 2-Methyl-4, 4'-bipyridyl. Schmalzl K and Summers L.Aust. J. Chem. 30(3) , 657-662, (1977)
Efficient synthesis of 4-, 5-, and 6-methyl-2, 2'-bipyridine by a Negishi cross-coupling strategy followed by high-yield conversion to bromo-and chloromethyl-2, 2'-bipyridines. Savage SA, et al.
J. Org. Chem. 63(26) , 10048-10051, (1998)