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1,3-Benzodithiol-1-ium tetrafluoroborate

Names

[ CAS No. ]:
57842-27-0

[ Name ]:
1,3-Benzodithiol-1-ium tetrafluoroborate

[Synonym ]:
1,3-Benzodithiol-2-ylium tetrafluoroborate
1,3-benzodithiol-3-ium,tetrafluoroborate
MFCD00070613
1,3-Benzodithiol-1-ium tetrafluoroborate

Chemical & Physical Properties

[ Melting Point ]:
150 °C (dec.)(lit.)

[ Molecular Formula ]:
C7H5BF4S2

[ Molecular Weight ]:
240.049

[ Exact Mass ]:
239.986191

[ PSA ]:
56.48000

[ LogP ]:
4.54390

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

A catalytic reactor for the organocatalyzed enantioselective continuous flow alkylation of aldehydes.

ChemSusChem 7(12) , 3534-40, (2014)

The use of immobilized metal-free catalysts offers the unique possibility to develop sustainable processes in flow mode. The challenging intermolecular organocatalyzed enantioselective alkylation of a...

Highly enantioselective α alkylation of aldehydes with 1,3-benzodithiolylium tetrafluoroborate: a formal organocatalytic α alkylation of aldehydes by the carbenium ion.

Angew. Chem. Int. Ed. Engl. 50(34) , 7842-6, (2011)

Triclinic polymorph of dibenzotetra-thia-fulvalene.

Acta Crystallogr. Sect. E Struct. Rep. Online 65(Pt 9) , o2083, (2009)

Crystals of the title compound (DBTTF), C(14)H(8)S(4), feature a triclinic polymorph different from two known monoclinic polymorphs. In this form, there are two independent centrosymmetric half-mol-ec...


More Articles


Related Compounds