2-Iodobenzyl chloride

Names

[ Name ]:
2-Iodobenzyl chloride

[Synonym ]:
2-Iodobenzyl chloride
1-(Chloromethyl)-2-iodobenzene
(2-iodophenyl)methyl chloride
1-Iodo-2-(chloromethyl)benzene
MFCD00000898
Benzene,1-(chloromethyl)-2-iodo
o-Iodobenzylchloride
Benzene, 1-(chloromethyl)-2-iodo-
2-iodo-(1-chloromethyl)benzene
Einecs 261-779-2

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
256.6±0.0 °C at 760 mmHg

[ Melting Point ]:
29-31 °C(lit.)

[ Molecular Formula ]:
C₇H₆ClI

[ Molecular Weight ]:
252.480

[ Flash Point ]:
115.0±20.4 °C

[ Exact Mass ]:
251.920258

[ LogP ]:
3.52

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.620

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34;R36/37

[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Synthesis of Succinimido[3,4-b]indane and 1,2,3,4,5,6-Hexahydro-1,5-methano-3-benzazocine-2,4-dione by Sequential Alkylation and Intramolecular Arylation of Enolates Derived from N,N,N'N'-Tetramethylbutanediamides and N,N,N'N'-Tetramethylpentanediamides.

J. Org. Chem. 64(5) , 1543-1553, (1999)

The tricyclic title compounds, 4 and 5, were synthesized by initial alkylation of the lithium monoenolates of N,N,N',N'-tetramethylbutanediamide (6) and N,N,N',N'-tetramethylpentanediamide (19) with 2...

An Approach to α-substituted Amines. Williams L, et al.

Tetrahedron 50(48) , 13697-13708, (1994)

1-Azatriene cyclisation as a route to annelated pyrido [4, 3-b] indoles. Gilchrist TL ,et al.

Tetrahedron 53(12) , 4447-56, (1997)