2,2,2-trichloroethyl acetate

Names

[ CAS No. ]:
625-24-1

[ Name ]:
2,2,2-trichloroethyl acetate

[Synonym ]:
2,2,2-trichloroethylethanoate
Ethanol,2,2,2-trichloro-,1-acetate
2,2,2-trichloroethylacetate
chloroform-methanolacetic acid
2,2,2',4'-TETRACHLOROACETOPHENONE

Chemical & Physical Properties

[ Density]:
1.401 g/mL at 20ºC(lit.)

[ Boiling Point ]:
238.3ºC at 760 mmHg

[ Molecular Formula ]:
C₄H₅Cl₃O₂

[ Molecular Weight ]:
191.44000

[ Flash Point ]:
105.7ºC

[ Exact Mass ]:
189.93600

[ PSA ]:
26.30000

[ LogP ]:
1.91970

[ Index of Refraction ]:
n20/D 1.457

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AJ8300000

CHEMICAL NAME :: Acetic acid, 2,2,2-trichloroethyl ester

CAS REGISTRY NUMBER :: 625-24-1

BEILSTEIN REFERENCE NO. :: 1757888

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C4-H5-Cl3-O2

MOLECULAR WEIGHT :: 191.44

WISWESSER LINE NOTATION :: GXGG1OV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 900 mg/kg

TOXIC EFFECTS :: Behavioral - sleep

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 63,183,1938

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Risk Phrases ]:
23/24/25

[ Safety Phrases ]:
36/37/39-45

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
AJ8300000

[ HS Code ]:
2915390090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915390090

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

Articles

M. Therisod, A.M. Klibanov

J. Am. Chem. Soc. 108 , 5638, (1986)

F. Theil et al.

Synthesis , 540, (1988)

G. Carrea et al.

J. Chem. Soc. Perkin Trans. I , 1057, (1989)