9-Oxabicyclo[6.1.0]non-4-ene
Names
[ CAS No. ]:
637-90-1
[ Name ]:
9-Oxabicyclo[6.1.0]non-4-ene
[Synonym ]:
1,2-Epoxy-5-cyclooctene,GC
9-OXABICYCLO[6.1.0]NON-4-ENE
cis-1,2-epoxy-5-cyclooctene
MFCD00086420
1,2-Epoxy-5-Cyclooctene (9-Oxabicyclo6.1.0Non-4-Ene
Cycloocta-1,5-diene epoxide
1,5-cyclooctadiene epoxide
1,5-cyclooctadiene monoepoxide
meso-cycloocta-1,5-diene oxide
EINECS 211-308-1
Chemical & Physical Properties
[ Density]:
1.013 g/mL at 25ºC(lit.)
[ Boiling Point ]:
195ºC(lit.)
[ Molecular Formula ]:
C8H12O
[ Molecular Weight ]:
124.18000
[ Flash Point ]:
158 °F
[ Exact Mass ]:
124.08900
[ PSA ]:
12.53000
[ LogP ]:
1.88400
[ Index of Refraction ]:
n20/D 1.495(lit.)
[ Storage condition ]:
0-6°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2932999099
Customs
[ HS Code ]: 2932999099
[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
ChemMedChem 6(3) , 424-7, (2011)
Intramolecular bromonium ion assisted epoxide ring-opening: capture of the oxonium ion with an added external nucleophile.
J. Org. Chem. 76(1) , 97-104, (2011)
9-Oxabicyclo[6.1.0]non-4-ene (1) undergoes intramolecular bromonium ion-assisted epoxide ring-opening using N-bromosuccinimide via a presumed oxonium ion that is subject to stereospecific, nonregiosel...
Transannular oxygen participation in halofluorination reactions of 9-oxabicyclo [6.1. 0] non-4-ene [1]. Haufe G, et al.J. Fluor. Chem. 46(1) , 83-95, (1990)