2,3-Diaminophenazine

Names

[ CAS No. ]:
655-86-7

[ Name ]:
2,3-Diaminophenazine

[Synonym ]:
2,3-Diaminophenazine
MFCD00160693
DAP
EINECS 211-512-0
2,3-diaminophenazene
phenazine-2,3-diyldiamine
2,3-diamino-phenazin
PHENAZINE-2,3-DIAMINE
2,3-Phenazinediamine
2,3-diamonophenazine
Phenazine,2,3-diamino

Biological Activity

[Description]:

2,3-Diaminophenazine (2,3-Phenazinediamine) is an amino derivative of phenazine with promising luminescence, electrochemical and biochemical applications[1][2].

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

[References]

[1]. Xiaoyue He, et al. Selective self-assembly of 2,3-diaminophenazine molecules on MoSe 2 mirror twin boundaries. Nat Commun. 2019 Jun 28;10(1):2847.

[2]. Feng Zhang, et al. An enzymatic ratiometric fluorescence assay for 6-mercaptopurine by using MoS 2 quantum dots. Mikrochim Acta. 2018 Nov 10;185(12):540.

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
497.8±15.0 °C at 760 mmHg

[ Melting Point ]:
>300ºC

[ Molecular Formula ]:
C₁₂H₁₀N₄

[ Molecular Weight ]:
210.235

[ Flash Point ]:
287.1±7.6 °C

[ Exact Mass ]:
210.090546

[ PSA ]:
77.82000

[ LogP ]:
1.82

[ Vapour Pressure ]:
0.0±1.3 mmHg at 25°C

[ Index of Refraction ]:
1.853

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SG1577650

CHEMICAL NAME :: Phenazine, 2,3-diamino-

CAS REGISTRY NUMBER :: 655-86-7

BEILSTEIN REFERENCE NO. :: 0014422

LAST UPDATED :: 199612

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C12-H10-N4

MOLECULAR WEIGHT :: 210.26

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Specific locus test

MUTATION DATA

TEST SYSTEM :: Insect - Drosophila melanogaster

DOSE/DURATION :: 4900 nmol/vial

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 369,75,1996

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;Xn: Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
26-36/37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
SG1577650

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Spectrophotometric quantification of horseradish peroxidase with o-phenylenediamine.

Anal. Biochem. 407(2) , 293-5, (2010)

The assay conditions for the spectrophotometric quantification of horseradish peroxidase (HRP) with the chromogenic substrate o-phenylenediamine (OPD) at 25°C in the presence of hydrogen peroxide (H(2...

Spectrophotometric quantification of lactose in solution with a peroxidase-based enzymatic cascade reaction system.

Anal. Bioanal. Chem 401 , 2307-2310, (2011)

A spectrophotometric assay was developed for the quantification of lactose in aqueous solution via a one-pot enzymatic cascade reaction at 25 °C and pH 7.2. Lactose (0.2-1.8 mM), E. coli β-galactosida...

Photoinduced DNA cleavage and cellular damage in human dermal fibroblasts by 2,3-diaminophenazine.

Photochem. Photobiol. 81(1) , 89-95, (2005)

Aromatic amines, such as o-phenylenediamine (OPD), have been used extensively in commercial hair dyes and in the synthesis of agricultural pesticides. Air oxidation of OPD results in the formation of ...