tebbe reagent
Names
Chemical & Physical Properties
[ Density]:
0.927
[ Molecular Formula ]:
C13H18AlClTi
[ Molecular Weight ]:
284.58400
[ Flash Point ]:
4ºC
[ Exact Mass ]:
284.03900
[ LogP ]:
4.36090
[ Appearance of Characters ]:
Solution | Dark red to purple
[ Storage condition ]:
Refrigerator
[ Water Solubility ]:
Soluble in toluene, benzene, dichloromethane. Insoluble in water.
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS07, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H304-H314-H336-H361d-H373
[ Precautionary Statements ]:
P210-P261-P280-P301 + P310-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Highlyflammable;T:Toxic;
[ Risk Phrases ]:
R11;R23/24/25;R34
[ Safety Phrases ]:
S16-S25-S29-S33-S36/37/39
[ RIDADR ]:
UN 2924 3/PG 2
[ WGK Germany ]:
2
[ Packaging Group ]:
II
[ Hazard Class ]:
4.3
[ HS Code ]:
29310099
Articles
Bioorg. Med. Chem. 11 , 2489-2497, (2003)
The Diels-Alder reaction between two polygodial-derived dienes and simple quinones to yield substituted naphtho- and anthraquinones, is described. The in vitro trypanocide activity for the series was ...
Synthesis of a novel ceramide analogue via Tebbe methylenation and evaluation of its antiproliferative activity.Org. Lett. 7 , 1645, (2005)
[reaction: see text] A new analogue of (2S,3R)-ceramide (2) with a methylene group at C4 has been synthesized from d-tartaric acid (3) by using Tebbe methylenation as the key step. Compound 2 exhibite...
Synthesis , 165, (1991)