sulfometuron-methyl [ANSI]
Names
[ CAS No. ]:
74222-97-2
[ Name ]:
sulfometuron-methyl [ANSI]
[Synonym ]:
methyl 2-{[(4,6-dimethylpyrimidin-2-yl)carbamoyl]sulfamoyl}benzoate
sulfometuron-methyl
DPX T5648
Sulfometuron methyl ester
methyl 2-(4,6-dimethylpyrimidin-2-ylcarbamoylsulfamoyl)benzoate
Methyl 2-{[(4,6-dimethyl-2-pyrimidinyl)carbamoyl]sulfamoyl}benzoate
methyl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate
Benzoic acid, 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-, methyl ester
methyl 2-[3-(4,6-dimethylpyrimidin-2-yl)ureidosulfonyl]benzoate
sulfometuron-methyl [ANSI]
T6N CNJ BMVMSWR BVO1& D1 F1
methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]benzoate
EINECS 277-780-6
2-[[[[(4,6-Dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]benzoic Acid Methyl Ester
MFCD00128060
N-[(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2-methoxycarbonylbenzenesulfonamide
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Melting Point ]:
203-205°C
[ Molecular Formula ]:
C15H16N4O5S
[ Molecular Weight ]:
364.376
[ Exact Mass ]:
364.084137
[ PSA ]:
135.73000
[ LogP ]:
2.18
[ Index of Refraction ]:
1.601
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DG9096550
- CHEMICAL NAME :
- Benzoic acid, o-((3-(4,6-dimethyl-2-pyrimidinyl)ureido)sulfonyl)-, methyl ester
- CAS REGISTRY NUMBER :
- 74222-97-2
- BEILSTEIN REFERENCE NO. :
- 0965602
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 8
- MOLECULAR FORMULA :
- C15-H16-N4-O5-S
- MOLECULAR WEIGHT :
- 364.41
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- DUPON* E.I. Dupont de Nemours and Company, Technical Sheet. (1007 Market St., Wilmington, DE 19898) Volume(issue)/page/year: AG-361 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DUPON* E.I. Dupont de Nemours and Company, Technical Sheet. (1007 Market St., Wilmington, DE 19898) Volume(issue)/page/year: AG-361
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >5 gm/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DUPON* E.I. Dupont de Nemours and Company, Technical Sheet. (1007 Market St., Wilmington, DE 19898) Volume(issue)/page/year: AG-361
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DUPON* E.I. Dupont de Nemours and Company, Technical Sheet. (1007 Market St., Wilmington, DE 19898) Volume(issue)/page/year: AG-361
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - duck
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,774,1991 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 5 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989
Safety Information
[ Symbol ]:
GHS09
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H400
[ Precautionary Statements ]:
P273
[ Personal Protective Equipment ]:
Eyeshields;Gloves
[ Hazard Codes ]:
N
[ Risk Phrases ]:
R50
[ Safety Phrases ]:
S61
[ RIDADR ]:
UN3077 9/PG 3
[ RTECS ]:
DG9096550
[ Hazard Class ]:
9.0
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Nucleic Acids Res. 42(13) , 8537-55, (2014)
Conserved ribosomal proteins frequently harbor additional segments in eukaryotes not found in bacteria, which could facilitate eukaryotic-specific reactions in the initiation phase of protein synthesi...
Constricted flux through the branched-chain amino acid biosynthetic enzyme acetolactate synthase triggers elevated expression of genes regulated by rpoS and internal acidification.J. Bacteriol. 180(4) , 785-92, (1998)
The first common enzyme of isoleucine and valine biosynthesis, acetolactate synthase (ALS), is specifically inhibited by the herbicide sulfometuron methyl (SM). To further understand the physiological...
Reduced transaminase B (IlvE) activity caused by the lack of yjgF is dependent on the status of threonine deaminase (IlvA) in Salmonella enterica serovar Typhimurium.J. Bacteriol. 186(3) , 803-10, (2004)
The YjgF/YER057c/UK114 family is a highly conserved class of proteins that is represented in the three domains of life. Thus far, a biochemical function demonstrated for these proteins in vivo or in v...