Zinc bromide
Names
[ CAS No. ]:
7699-45-8
[ Name ]:
Zinc bromide
[Synonym ]:
MFCD00011294
Zinc dibromide
EINECS 231-718-4
Chemical & Physical Properties
[ Density]:
4.22
[ Boiling Point ]:
697ºC
[ Melting Point ]:
394ºC
[ Molecular Formula ]:
Br2Zn
[ Molecular Weight ]:
225.217
[ Flash Point ]:
650°C
[ Exact Mass ]:
221.765808
[ LogP ]:
1.68870
[ Index of Refraction ]:
1.5452
[ Storage condition ]:
APPROX >0°C
[ Stability ]:
Stable. Forms explosive mixtures with sodium and potassium. Protect from moisture.
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- ZH1150000
- CHEMICAL NAME :
- Zinc bromide
- CAS REGISTRY NUMBER :
- 7699-45-8
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 4
- MOLECULAR FORMULA :
- Br2-Zn
- MOLECULAR WEIGHT :
- 225.19
- WISWESSER LINE NOTATION :
- .ZN..E2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
MUTATION DATA
- TYPE OF TEST :
- Cytogenetic analysis
- TEST SYSTEM :
- Rodent - rat Ascites tumor
- DOSE/DURATION :
- 800 mg/kg
- REFERENCE :
- GANNA2 Gann. Japanese Journal of Cancer Research. (Tokyo, Japan) V.1-75, 1907-84. For publisher information, see JJCREP. Volume(issue)/page/year: 54,155,1963 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83367 No. of Facilities: 22 (estimated) No. of Industries: 2 No. of Occupations: 1 No. of Employees: 68 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83367 No. of Facilities: 221 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 442 (estimated) No. of Female Employees: 221 (estimated)
Safety Information
[ Symbol ]:
GHS05, GHS07, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H302-H314-H317-H411
[ Precautionary Statements ]:
P273-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C:Corrosive
[ Risk Phrases ]:
R34;R50
[ Safety Phrases ]:
S26-S29-S36/37/39-S45-S61
[ RIDADR ]:
UN 3260
[ WGK Germany ]:
3
[ RTECS ]:
ZH1150000
[ Packaging Group ]:
II
[ Hazard Class ]:
8
Articles
Chem. Pharm. Bull. 57(10) , 1158-60, (2009)
Asymmetric intermolecular hydroacylation between salicylaldehyde (1) and 1,5-hexadiene (2) using a combination of [RhCl(C(8)H(14))(2)](2) (0.10 eq), (S)-BINAP (0.10 eq), and ZnBr(2) (0.20 eq) afforded...
Palladium-catalyzed cross-coupling of cyclopropylmagnesium bromide with aryl bromides mediated by zinc halide additives.J. Org. Chem. 75(19) , 6677-80, (2010)
The key Pd-catalyzed cross-coupling of aryl bromides or triflates and cyclopropylmagnesium bromide in the presence of substoichiometric amounts of zinc bromide produces cyclopropyl arenes in good to e...
Synthesis of tri- or tetrasubstituted pyrimidine derivatives through the [5+1] annulation of enamidines with either N,N-dimethylformamide dialkyl acetals or orthoesters and their application in a ring transformation of pyrimidines to pyrido[2,3-d]pyrimidin-5-one derivatives.Chemistry 17(34) , 9385-94, (2011)
The [5+1] annulation of enamidines, which were prepared from functionalized silanes, organolithium compounds and two nitriles, with N,N-dimethylformamide dialkyl acetals as the C1 unit is described, l...