1-(tert-Butyldimethylsilyloxy)-1-methoxyethene
Names
[ CAS No. ]:
77086-38-5
[ Name ]:
1-(tert-Butyldimethylsilyloxy)-1-methoxyethene
[Synonym ]:
MFCD02683524
TBS-methoxyethene
Chemical & Physical Properties
[ Density]:
0.863 g/mL at 25ºC(lit.)
[ Boiling Point ]:
62ºC9 mm Hg(lit.)
[ Molecular Formula ]:
C9H20O2Si
[ Molecular Weight ]:
188.33900
[ Flash Point ]:
125 °F
[ Exact Mass ]:
188.12300
[ PSA ]:
18.46000
[ LogP ]:
3.12580
[ Index of Refraction ]:
n20/D 1.429(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F+
[ Risk Phrases ]:
10
[ RIDADR ]:
UN 1993 3/PG 3
[ Hazard Class ]:
3.0
[ HS Code ]:
2931900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Tetrahedron Lett. 51(21) , 2855-2858, (2010)
Recent developments in the syntheses of the epothilones and related analogues. Watkins EB, et al.
European J. Org. Chem. 18 , 4071-4084, (2006)
Enantioselective addition of ketene silyl acetals to nitrones catalyzed by chiral titanium complexes. Synthesis of optically active ß-amino acids. Murahashi SI, et al.
J. Am. Chem. Soc. 124(12) , 2888-2889, (2002)