Sodamide

[ Density]:
1.4

[ Boiling Point ]:
400 °C(lit.)

[ Melting Point ]:
210 °C(lit.)

[ Molecular Formula ]:
H₂NNa

[ Molecular Weight ]:
39.012

[ Flash Point ]:
85 °F

[ Exact Mass ]:
39.008495

[ PSA ]:
26.02000

[ LogP ]:
0.10970

[ Water Solubility ]:
REACTS VERY VIOLENTLY, EVEN EXPLOSIVELY

Click to get detail MSDS

[ Symbol ]:

GHS02, GHS05, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H261-H314-H400

[ Supplemental HS ]:
Contact with water liberates toxic gas., May form explosive peroxides.

[ Precautionary Statements ]:
P231 + P232-P273-P280-P305 + P351 + P338-P310-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R14/15;R19;R34

[ Safety Phrases ]:
S26-S43-S45-S62-S7/8-S43D-S36/37/39-S27-S16

[ RIDADR ]:
UN 3129 4.3/PG 2

[ WGK Germany ]:
2

[ Packaging Group ]:
II

[ Hazard Class ]:
4.3

[ HS Code ]:
2853009090

[ HS Code ]: 2853009090

Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2.

Dalton Trans. 43(46) , 17324-32, (2014)

Trivalent Eu[N(SiHMe2)2]3(THF)2 can easily be synthesized by applying a routine salt metathesis protocol (EuCl3(THF)2 and 3 equiv. of Li[N(SiHMe2)2] in n-hexane) which crystallizes isotypically to its...

Isotopic studies of the ammonia decomposition reaction mediated by sodium amide.

Phys. Chem. Chem. Phys. 17 , 22999-3006, (2015)

We demonstrate that the ammonia decomposition reaction catalysed by sodium amide proceeds under a different mechanism to ammonia decomposition over transition metal catalysts. Isotopic variants of amm...

Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides.

Org. Biomol. Chem. 9 , 2743-2750, (2011)

Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with ...

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