di-tert-butylsilyl bis(trifluoromethanesulfonate)
Names
[ CAS No. ]:
85272-31-7
[ Name ]:
di-tert-butylsilyl bis(trifluoromethanesulfonate)
[Synonym ]:
di-tert-butylsilanediyl bis(trifluoromethanesulfonate)
Di(tert-butyl)([(trifluoromethyl)sulfonyl]oxy)silyl trifluoromethanesulfonate
[ditert-butyl(trifluoromethylsulfonyloxy)silyl] trifluoromethanesulfonate
Bis(2-methyl-2-propanyl)silanediyl bis(trifluoromethanesulfonate)
MFCD00010581
Methanesulfonic acid, 1,1,1-trifluoro-, bis(1,1-dimethylethyl)silylene ester
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
275.6±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C10H18F6O6S2Si
[ Molecular Weight ]:
440.452
[ Flash Point ]:
90.6±0.0 °C
[ Exact Mass ]:
440.021820
[ PSA ]:
103.50000
[ LogP ]:
6.36
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.413
MSDS
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C: Corrosive;
[ Risk Phrases ]:
R34
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
8
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Org. Lett. 7 , 5769, (2005)
[structures: see text] A versatile (S)-3-(hydroxymethyl)butane-1,2,4-triol building block has been synthesized starting from D-isoascorbic acid, a common food preservative. The key transformation in t...
Z. Anorg. Allg. Chem. 618 , 144, (1992)
Chem. Ber. 125 , 47, (1992)