[(1,2,5,6-eta)-1,5-Cyclooctadiene][1-[(4R,5R)-4,5-dihydro-5-methyl-2-phenyl-4-oxazolyl]-2-phenyl-1-(phenylmethyl)ethyl dicyclohexylphosphinite]iridium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Names

[ Name ]:
[(1,2,5,6-eta)-1,5-Cyclooctadiene][1-[(4R,5R)-4,5-dihydro-5-methyl-2-phenyl-4-oxazolyl]-2-phenyl-1-(phenylmethyl)ethyl dicyclohexylphosphinite]iridium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

[Synonym ]:
MFCD18252665

Chemical & Physical Properties

[ Melting Point ]:
160-161°C

[ Molecular Formula ]:
C₇₇H₇₀BF₂₄IrNO₃P

[ Molecular Weight ]:
1747.35000

[ Exact Mass ]:
1747.44000

[ PSA ]:
57.70000

[ LogP ]:
22.72760

[ Appearance of Characters ]:
Powder

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

Articles

A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes We thank Dr. Martin Studer and Dr. Beno_t Pugin (Solvias AG, Basel) for fruitful discussions, and Prof. Kevin Burgess (Texas A&M University) for preprints of related unpublished work. Financial support by the Swiss National Science Foundation is gratefully acknowledged.

Angew. Chem. Int. Ed. Engl. 40 , 4445-4447, (2001)

Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation. Menges, F. and Pfaltz, A.

Adv. Synth. Catal. 344 , 40-44, (2002)