S,S-DIMETHYL N-(2,2,2-TRICHLOROETHOXYSULFONYL)-CARBONIMIDODITHIONATE

Names

[ Name ]:
S,S-DIMETHYL N-(2,2,2-TRICHLOROETHOXYSULFONYL)-CARBONIMIDODITHIONATE

[Synonym ]:
[(2,2,2-Trichloroethoxy)sulfonyl)]-carbonimidodithionic acid dimethyl ester
S,S-Dimethyl N-(2,2,2-trichloroethoxysulfonyl)carbonimidodithionate

Chemical & Physical Properties

[ Density]:
1.62g/cm3

[ Boiling Point ]:
393.5ºC at 760 mmHg

[ Melting Point ]:
69-73ºC

[ Molecular Formula ]:
C₅H₈Cl₃NO₃S₃

[ Molecular Weight ]:
332.67600

[ Flash Point ]:
191.8ºC

[ Exact Mass ]:
330.87300

[ PSA ]:
114.71000

[ LogP ]:
3.78080

[ Index of Refraction ]:
1.591

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
22-34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 3261 8/PG 2

Articles

Expanding the substrate scope for C-H amination reactions: oxidative cyclization of urea and guanidine derivatives.

Org. Lett. 8 , 1073, (2006)

[reaction: see text] Oxidative C-H amination of N-trichloroethoxysulfonyl-protected ureas and guanidines is demonstrated to proceed in high yield for tertiary and benzylic-derived substrates. The succ...

Editorial 2006: exciting and challenging times for organic letters.

Org. Lett. 8 , 1, (2006)