Bis[di-(tert-butyl)(4-trifluoromethylphenyl)phosphine]palladium(II) chloride
Names
[ CAS No. ]:
887919-36-0
[ Name ]:
Bis[di-(tert-butyl)(4-trifluoromethylphenyl)phosphine]palladium(II) chloride
[Synonym ]:
ditert-butyl-[4-(trifluoromethyl)phenyl]phosphane,dichloropalladium
Chemical & Physical Properties
[ Molecular Formula ]:
C30H44Cl2F6P2Pd
[ Molecular Weight ]:
757.93400
[ Exact Mass ]:
756.12300
[ PSA ]:
27.18000
[ LogP ]:
4.82720
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ RIDADR ]:
NONH for all modes of transport
Articles
Org. Lett. 8 , 1787, (2006)
[reaction: see text] New air-stable PdCl(2){P(t)Bu(2)(p-R-Ph)}(2) (R = H, NMe(2), CF(3),) complexes represent simple, general, and efficient catalysts for the Suzuki-Miyaura cross-coupling reactions o...
New catalysts for Suzuki-Miyaura coupling reactions of heteroatom-substituted heteroaryl chlorides.J. Org. Chem. 72 , 5104, (2007)
The new air-stable PdCl2[PR2(Ph-R')]2 complexes, readily prepared from commercial reagents, exhibit unique efficiency as catalysts for the Suzuki-Miyaura coupling reactions of a variety of heteroatom-...