(11BS, 11'BS)-4,4'-(OXYDI-2,1-PHENYLENE&
Names
[ CAS No. ]:
898830-89-2
[ Name ]:
(11BS, 11'BS)-4,4'-(OXYDI-2,1-PHENYLENE&
[Synonym ]:
4,4'-(Oxydi-2,1-phenylene)bis(dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine)
R, R-Reetz D-Diphosphonite
MFCD09842741
S, S-Reetz D-Diphosphonite
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4,4'-(oxydi-2,1-phenylene)bis-
Chemical & Physical Properties
[ Molecular Formula ]:
C52H32O5P2
[ Molecular Weight ]:
798.755
[ Exact Mass ]:
798.172485
[ LogP ]:
15.97
Safety Information
[ Symbol ]:
GHS02, GHS07, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H228-H315-H336-H361d-H373
[ Precautionary Statements ]:
P210-P261-P281
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ RIDADR ]:
UN 3175 4.1 / PGII
Articles
Org. Lett. 3 , 4083, (2001)
[reaction: see text] BINOL-based diphosphonites having achiral backbones are useful ligands in the Rh-catalyzed conjugate addition of arylboronic acids to alpha,beta-unsaturated carbonyl compounds. Th...
Reetz, M. T.; Li, X.Adv. Synth. Catal. 348 , 1157, (2006)