4,7-Dimethoxy-1,10-phenanthroline

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
373.1±37.0 °C at 760 mmHg

[ Melting Point ]:
197-212ºC

[ Molecular Formula ]:
C₁₄H₁₂N₂O₂

[ Molecular Weight ]:
240.257

[ Flash Point ]:
135.9±16.8 °C

[ Exact Mass ]:
240.089874

[ PSA ]:
44.24000

[ LogP ]:
2.31

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.667

Click to get detail MSDS

[ Symbol ]:

GHS05, GHS07, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H318-H400

[ Precautionary Statements ]:
P273-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;

[ Risk Phrases ]:
22-41-50

[ Safety Phrases ]:
26-39-61

[ RIDADR ]:
UN 3077 9/PG 3

[ HS Code ]:
2933990090

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

4,7-Dimethoxy-1,10-phenanthroline: an excellent ligand for the Cu-catalyzed N-arylation of imidazoles.

Org. Lett. 8 , 2779, (2006)

[reaction: see text] 4,7-Dimethoxy-1,10-phenanthroline (L) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazole with aryl iodides and bromides under mild conditions. A...

Copper-catalyzed N-arylation of imidazoles and benzimidazoles.

J. Org. Chem. 72 , 6190, (2007)

4,7-Dimethoxy-1,10-phenanthroline (L1c) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazoles and benzimidazoles with both aryl iodides and bromides under mild conditi...

A general and efficient copper catalyst for the amidation of aryl halides.

J. Am. Chem. Soc. 124 , 7421, (2002)

An experimentally simple and inexpensive catalyst system was developed for the amidation of aryl halides by using 0.2-10 mol % of CuI, 5-20 mol % of a 1,2-diamine ligand, and K(3)PO(4), K(2)CO(3), or ...

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