2-((三丁基锡烷基)甲氧基)丙烷-1-胺
2-((三丁基锡烷基)甲氧基)丙烷-1-胺结构式
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常用名 | 2-((三丁基锡烷基)甲氧基)丙烷-1-胺 | 英文名 | SnAP 2Me-M Reagent |
|---|---|---|---|---|
| CAS号 | 1557288-07-9 | 分子量 | 378.18 | |
| 密度 | 1.128 at 25℃ | 沸点 | 379.0±48.0 °C(Predicted) | |
| 分子式 | C16H37NOSn | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS06, GHS09 |
信号词 | Danger |
| 中文名 | 2-((三丁基锡烷基)甲氧基)丙烷-1-胺 |
|---|---|
| 英文名 | SnAP 2Me-M Reagent |
| 密度 | 1.128 at 25℃ |
|---|---|
| 沸点 | 379.0±48.0 °C(Predicted) |
| 分子式 | C16H37NOSn |
| 分子量 | 378.18 |
| 外观性状 | liquid |
| 折射率 | n/D1.487 |
| 储存条件 | -20°C |
| 符号 |
GHS06, GHS09 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H301 + H311 + H331-H315-H319-H335-H410 |
| 警示性声明 | P261-P273-P280-P301 + P310-P305 + P351 + P338-P311 |
| 危险品运输编码 | UN 2788 6.1 / PGIII |
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SnAP reagents for the transformation of aldehydes into substituted thiomorpholines--an alternative to cross-coupling with saturated heterocycles.
Angew. Chem. Int. Ed. Engl. 52(6) , 1705-8, (2013)
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SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.
Nature Chemistry 6(4) , 310-4, (2014) Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially ... |
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One-step synthesis of saturated spirocyclic N-heterocycles with stannyl amine protocol (SnAP) reagents and ketones.
J. Am. Chem. Soc. 136(51) , 17726-9, (2014) The combination of cyclic ketones and stannyl amine protocol (SnAP) reagents affords saturated, spirocyclic N-heterocycles under operationally simple reaction conditions. The resulting, N-unprotected ... |
