五水合硝酸铋

五水合硝酸铋用途

【用途一】
用于制造铋盐、制药等
【用途二】
用于制造其他铋盐、显像管和发光漆等
【用途三】
用于制造其他铋盐。生物碱的沉淀。制各种催化剂原料。发光油漆。搪瓷。
【用途四】
用于制造铋盐、制药、作化学试剂等。
【用途五】
沉淀生物碱，钠、铷和铯的试剂，原子吸收光谱标准制备。制造其他铋盐。

五水合硝酸铋名称

[ CAS 号 ]:
10035-06-0

[ 中文名 ]:
硝酸铋(III) 五水合物

[ 英文名 ]:
Bismuth nitrate pentahydrate

[中文别名 ]:

[英文别名 ]:

EINECS 233-791-8
MFCD00149157
Bismuth(III) nitrate pentahydrate
bismuth,trinitrate,pentahydrate

五水合硝酸铋物理化学性质

[ 密度 ]:
2,83 g/cm3

[ 沸点 ]:
75-80 °C(lit.)

[ 熔点 ]:
30 °C(lit.)

[ 分子式 ]:
BiH₁₀N₃O₁₄

[ 分子量 ]:
485.07200

[ 精确质量 ]:
484.99700

[ PSA ]:
252.79000

[ LogP ]:
0.53080

[ 外观性状 ]:
无色晶体

[ 储存条件 ]:
库房通风,轻装轻卸,与有机物、还原剂、木炭、硫磷易燃物分开存放

[ 稳定性 ]:
Stable. Incompatible with strong acids, strong reducing agents, organic materials, finely powdered metals, moisture. Strong oxidizer.

[ 水溶解性 ]:
MAY DECOMPOSE

五水合硝酸铋MSDS

详细MSDS(安全技术说明书)

五水合硝酸铋毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EB2984430

CAS REGISTRY NUMBER :: 10035-06-0

LAST UPDATED :: 199606

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: Bi-N3-O9.5H2-O

MOLECULAR WEIGHT :: 485.11

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4042 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(6),16,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 3710 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(6),16,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 71 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JTCTDW Journal of Toxicology, Clinical Toxicology. (Marcel Dekker, 270 Madison Ave., New York, NY 10016) V.19- 1982- Volume(issue)/page/year: 20,159,1983 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2 mg/m3/17W-I

TOXIC EFFECTS :: Cardiac - EKG changes not diagnostic of specified effects Endocrine - hypoglycemia Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(6),16,1986

五水合硝酸铋安全信息

[ 符号 ]:

GHS03, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H272-H315-H319-H335

[ 警示性声明 ]:
P210-P220-P221-P305 + P351 + P338-P370 + P378

[ 个人防护装备 ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
O: Oxidizing agent;Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38;R8

[ 安全声明 (欧洲) ]:
S17-S26-S36-S37/39

[ 危险品运输编码 ]:
UN 1477 5.1/PG 2

[ WGK德国 ]:
2

[ RTECS号 ]:
EB2984430

[ 包装等级 ]:
II

[ 危险类别 ]:
5.1

五水合硝酸铋制备

1.将氧化铋加入盛有蒸馏水的反应器中，缓慢加人浓硝酸进行反应，把反应完成溶液经蒸发浓缩、冷却结晶、离心分离，制得五水硝酸铋。其反应方程式如下：

2.取分析纯硝酸，用水稀释形成溶液。加热至60～70℃后，逐渐加入颗粒状金属铋。待反应完毕后，过滤。重复上述步骤直至所有的金属铋溶解。将上述过程得到的滤液混合，蒸发至相对密度为19。冷却结晶，再吸滤，于40～50℃干燥，即得纯品硝酸铋。

3.将20g金属铋一点一点地加入40mL浓硝酸(68%)中，使其溶解，然后水浴加热浓缩至溶液呈淡黄色。冷却结晶。抽滤，用冷的浓硝酸洗涤。夹在滤纸间干燥。

4.将密度为1.4的分析纯硝酸，用纯水稀释一倍，加热至60～70℃，逐渐加入适量金属铋，进行反应：

反应结束后，过滤，未溶金属铋再用上述硝酸溶液溶解，在60～70℃下继续反应至差不多全部溶解，与上述滤液合并，在60～70℃下蒸发至密度为1.9时，搅拌，用冰冷却结晶、过滤、甩干，在40～45℃下干燥一会儿即可。若含有较多铁杂质，则应先加水，用硝酸调ph值为1～2，沉淀出次硝酸铋，使Fe³⁺离子留在水溶液中，然后用硝酸溶解沉淀，再蒸发浓缩、结晶、干燥。

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